SiO2和Al2O3固载铜盐作为苯酚氨基甲基化的有效催化剂

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-08-16 DOI:10.1007/s11172-025-4704-5

M. G. Shaibakova, L. K. Dilmukhametova, I. R. Ramazanov

引用次数: 0

摘要

采用选择性一锅法合成了取代2-（二甲氨基甲基）苯酚，收率为90-98%。该方法是在SiO2和Al2O3固载的铜(i)盐催化下，苯酚与二（二甲氨基）甲烷反应

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Copper salts immobilized on SiO2 and Al2O3 as effective catalysts for aminomethylation of phenols

A selective one-pot synthesis of substituted 2-(dimethylaminomethyl)phenols has been developed, affording yields of 90–98%. The method is based on the reaction of phenols with bis(dimethylamino)methane, catalyzed by copper(i) salts immobilized on SiO₂ and Al₂O₃

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.