新型双功能硫代亚甲基吡啶接枝聚合物树脂在酸性溶液中除汞

Nikhilesh Iyer , Ritesh Ruhela , Suvarna Saundarajan , Sanjukta Abhay Kumar , Dhruva Kumar Singh
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引用次数: 0

摘要

这项工作提出了一种新的多孔固体吸附剂,巯基亚甲基吡啶(TMP)配体接枝聚合物树脂(TMP树脂),用于在广泛的酸度范围内选择性除汞,其中双官能团迎合了水溶液中Hg2 +的阳离子和阴离子的吸附。TMP树脂对Hg2+在高酸性和低酸性溶液(氯介质)中的定量吸附能力在70-80 mg Hg/g范围内,表明阳离子和阴离子形式的Hg2+都能以(HgCl4)2-的形式吸附,从而利用了TMP配体的双官能性。金属-配体相互作用的光谱研究以及DFT计算表明了两种不同的机制,一种是在较低酸度下倾向于软-软配位配合,另一种是在较高酸度下汞-氯配合物与吡啶基团的阴离子交换。在0.1 M硫脲溶液中,以0.1 M HCl的浓度,对Hg2+进行了近乎完全的反萃取。树脂可再生至5次重复加载和洗脱,其中在Hg2+吸附方面没有明显的变化;解吸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Novel bifunctional thio-methylene-pyridine grafted polymeric resin for mercury removal from acidic solutions
This work brings forth a novel porous solid sorbent, thio-methylene-pyridine (TMP) ligand grafted polymeric resin (TMP resin), for selective mercury removal over a wide range of acidity in which the bi-functional group catered to sorption of both cationic and anionic species of Hg2 + in aqueous hydrochloric acid medium. TMP resin showed quantitative sorption of ‘Hg2+’ in high as well as low acidic solutions (chloride medium) with uptake capacity in the range of 70–80 mg Hg/g, indicating sorption of ‘Hg2+’ in both cationic and anionic form as (HgCl4)2-, hence utilizing the bi-functionality of TMP ligand. Spectroscopic investigation on metal-ligand interactions, as well as DFT calculations indicated towards two separate mechanisms, one being preference for soft-soft co-ordinate complexation at lower acidity and other being anion exchange of Hg-chloride complex by pyridinium group at higher acidity. Near complete back extraction of Hg2+ from the Hg-loaded sorbent was achieved using 0.1 M thiourea solution at 0.1 M HCl. Resin was regenerated upto 5 cycles of repeated loading and elution wherein there was no appreciable change in the performance with respect to Hg2+ sorption & desorption.
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