{"title":"利用新鲜棕榈果束和医用塑料废物共热解生产生物汽油,用于火花点火发动机","authors":"Nathawat Unsomsri , Khanes Chunyok , Watcharapol Pakdee , Phakwan Muncharoenporn , Patchara Koedthong , Sittinun Tawkaew , Songkran Wiriyasart , Sommas Kaewluan","doi":"10.1016/j.jaap.2025.107332","DOIUrl":null,"url":null,"abstract":"<div><div>This work examines the co-pyrolysis of fresh palm fruit bunches (FFB) together with used medical saline bottles (UMSB) as an environmentally sustainable approach for biogasoline production. Three FFB:UMSB feed ratios (100:0, 75:25, and 50:50) were evaluated in a batch pyrolyzer at 450 °C to assess bio-oil yield, product distribution, and fuel quality. The bio-oil obtained was separated via fractional distillation into biogasoline and diesel-range fractions. GC–MS and FTIR analyses indicated that higher UMSB proportions increased light hydrocarbon levels while decreasing oxygen-containing compounds. The 50:50 blend achieved the highest biogasoline yield (87.7 %) with favorable properties including higher heating value (42.6 MJ/kg), low viscosity (0.88 cSt), and reduced acidity (pH 3.6). Engine tests using a 2 kW spark-ignition generator showed stable combustion, extended runtime (19.6 hr), and comparable electrical efficiency (16.8 %) to commercial gasoline (15.4 %). Emission measurements indicated significant reductions in CO (64 %) and NO<sub>x</sub> (7.1 %) for the 50:50 blend. A simplified economic analysis showed cost competitiveness, with a production cost of 0.1 EUR/L and a profit margin of 0.8 EUR/L. The findings highlight co-pyrolysis as a promising circular-economy approach for converting palm biomass and plastic waste into value-added products via decentralized energy generation.</div></div>","PeriodicalId":345,"journal":{"name":"Journal of Analytical and Applied Pyrolysis","volume":"192 ","pages":"Article 107332"},"PeriodicalIF":6.2000,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Biogasoline production from co-pyrolysis of fresh palm fruit bunches and medical plastic waste for use in spark-ignition engines\",\"authors\":\"Nathawat Unsomsri , Khanes Chunyok , Watcharapol Pakdee , Phakwan Muncharoenporn , Patchara Koedthong , Sittinun Tawkaew , Songkran Wiriyasart , Sommas Kaewluan\",\"doi\":\"10.1016/j.jaap.2025.107332\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This work examines the co-pyrolysis of fresh palm fruit bunches (FFB) together with used medical saline bottles (UMSB) as an environmentally sustainable approach for biogasoline production. Three FFB:UMSB feed ratios (100:0, 75:25, and 50:50) were evaluated in a batch pyrolyzer at 450 °C to assess bio-oil yield, product distribution, and fuel quality. The bio-oil obtained was separated via fractional distillation into biogasoline and diesel-range fractions. GC–MS and FTIR analyses indicated that higher UMSB proportions increased light hydrocarbon levels while decreasing oxygen-containing compounds. The 50:50 blend achieved the highest biogasoline yield (87.7 %) with favorable properties including higher heating value (42.6 MJ/kg), low viscosity (0.88 cSt), and reduced acidity (pH 3.6). Engine tests using a 2 kW spark-ignition generator showed stable combustion, extended runtime (19.6 hr), and comparable electrical efficiency (16.8 %) to commercial gasoline (15.4 %). Emission measurements indicated significant reductions in CO (64 %) and NO<sub>x</sub> (7.1 %) for the 50:50 blend. A simplified economic analysis showed cost competitiveness, with a production cost of 0.1 EUR/L and a profit margin of 0.8 EUR/L. The findings highlight co-pyrolysis as a promising circular-economy approach for converting palm biomass and plastic waste into value-added products via decentralized energy generation.</div></div>\",\"PeriodicalId\":345,\"journal\":{\"name\":\"Journal of Analytical and Applied Pyrolysis\",\"volume\":\"192 \",\"pages\":\"Article 107332\"},\"PeriodicalIF\":6.2000,\"publicationDate\":\"2025-08-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Analytical and Applied Pyrolysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0165237025003857\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical and Applied Pyrolysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0165237025003857","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Biogasoline production from co-pyrolysis of fresh palm fruit bunches and medical plastic waste for use in spark-ignition engines
This work examines the co-pyrolysis of fresh palm fruit bunches (FFB) together with used medical saline bottles (UMSB) as an environmentally sustainable approach for biogasoline production. Three FFB:UMSB feed ratios (100:0, 75:25, and 50:50) were evaluated in a batch pyrolyzer at 450 °C to assess bio-oil yield, product distribution, and fuel quality. The bio-oil obtained was separated via fractional distillation into biogasoline and diesel-range fractions. GC–MS and FTIR analyses indicated that higher UMSB proportions increased light hydrocarbon levels while decreasing oxygen-containing compounds. The 50:50 blend achieved the highest biogasoline yield (87.7 %) with favorable properties including higher heating value (42.6 MJ/kg), low viscosity (0.88 cSt), and reduced acidity (pH 3.6). Engine tests using a 2 kW spark-ignition generator showed stable combustion, extended runtime (19.6 hr), and comparable electrical efficiency (16.8 %) to commercial gasoline (15.4 %). Emission measurements indicated significant reductions in CO (64 %) and NOx (7.1 %) for the 50:50 blend. A simplified economic analysis showed cost competitiveness, with a production cost of 0.1 EUR/L and a profit margin of 0.8 EUR/L. The findings highlight co-pyrolysis as a promising circular-economy approach for converting palm biomass and plastic waste into value-added products via decentralized energy generation.
期刊介绍:
The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.