平面、扭曲和弯曲π扩展吡咯[3,2-b]吡咯：合成、性质和应用的新进展[j]。化学8/2025)

IF 2.7 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-08-14 DOI:10.1002/ajoc.70145

Shivangi Gupta, Puneet Gupta

{"title":"平面、扭曲和弯曲π扩展吡咯[3,2-b]吡咯：合成、性质和应用的新进展[j]。化学8/2025)","authors":"Shivangi Gupta, Puneet Gupta","doi":"10.1002/ajoc.70145","DOIUrl":null,"url":null,"abstract":"<p>The cover image illustrates a reaction where two reactants react in the presence of the palladium catalyst via divergent pathways depending on the ligand environment. The presence of different ligands (L1 and L2) directs the catalytic cycle through distinct mechanistic routes, ultimately yielding two different products. This highlights the pivotal role of ligand identity in dictating reaction selectivity and product outcome. More details can be found in article number e202400819 by Shivangi Gupta and Puneet Gupta. \n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 8","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://aces.onlinelibrary.wiley.com/doi/epdf/10.1002/ajoc.70145","citationCount":"0","resultStr":"{\"title\":\"Cover Feature: Ligand-Induced Selectivity in the Reaction of Conjugated Enyne with Enolic Ester: A DFT-Based Mechanistic Study (Asian J. Org. Chem. 8/2025)\",\"authors\":\"Shivangi Gupta, Puneet Gupta\",\"doi\":\"10.1002/ajoc.70145\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The cover image illustrates a reaction where two reactants react in the presence of the palladium catalyst via divergent pathways depending on the ligand environment. The presence of different ligands (L1 and L2) directs the catalytic cycle through distinct mechanistic routes, ultimately yielding two different products. This highlights the pivotal role of ligand identity in dictating reaction selectivity and product outcome. More details can be found in article number e202400819 by Shivangi Gupta and Puneet Gupta. \\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":130,\"journal\":{\"name\":\"Asian Journal of Organic Chemistry\",\"volume\":\"14 8\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2025-08-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://aces.onlinelibrary.wiley.com/doi/epdf/10.1002/ajoc.70145\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://aces.onlinelibrary.wiley.com/doi/10.1002/ajoc.70145\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://aces.onlinelibrary.wiley.com/doi/10.1002/ajoc.70145","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

这个封面融合了Mohammad Bagher Teimouri及其同事的review e202500565的核心概念和伊朗文化元素。pyrrolo[3,2-b]pyrroles独特的3D结构体现在云层的弯曲形式和扭曲的飞毯上。它们的主要特征是光物理性质，其标志是嵌入吡咯的3D分子发出的光，照亮了地毯。波斯地毯被广泛认为是伊朗手工艺品的主要文化象征，而受到波斯微型艺术启发的风格云，通过丰富的文化和富有想象力的镜头，共同突出了科学主题。画面的整体氛围有点像《一千零一夜的故事》（中东民间故事集）。图片来源：Azadeh Badiee Dezfuly和Seyed Parsa Hashemian。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Ligand-Induced Selectivity in the Reaction of Conjugated Enyne with Enolic Ester: A DFT-Based Mechanistic Study (Asian J. Org. Chem. 8/2025)

查看原文本刊更多论文

Cover Feature: Ligand-Induced Selectivity in the Reaction of Conjugated Enyne with Enolic Ester: A DFT-Based Mechanistic Study (Asian J. Org. Chem. 8/2025)

The cover image illustrates a reaction where two reactants react in the presence of the palladium catalyst via divergent pathways depending on the ligand environment. The presence of different ligands (L1 and L2) directs the catalytic cycle through distinct mechanistic routes, ultimately yielding two different products. This highlights the pivotal role of ligand identity in dictating reaction selectivity and product outcome. More details can be found in article number e202400819 by Shivangi Gupta and Puneet Gupta.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.