高温改性Cs2SO4的晶体结构

IF 0.6 4区材料科学 Q4 MATERIALS SCIENCE, CERAMICS

Glass Physics and Chemistry Pub Date : 2025-08-12 DOI:10.1134/S1087659625600255

A. P. Shablinskii, Ya. P. Biryukov, M. G. Krzhizhanovskaya, R. S. Bubnova, S. K. Filatov

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引用次数: 0

摘要

本文介绍了α-Cs2SO4在800℃温度下边缘和顶点模型晶体结构的细化结果。氧原子位点的排列，不像Cs和S位点那样是对称固定的，被澄清了。结果表明，该边缘模型较好地符合实验数据，满足晶体化学参数。然而，顶点模型中的键长与已发表的数据更吻合。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal Structure of a High-Temperature Modification of Cs2SO4

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Crystal Structure of a High-Temperature Modification of Cs2SO4

This article presents the results of the refinement of the crystal structure of α-Cs₂SO₄ at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms’ sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.

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来源期刊

Glass Physics and Chemistry 工程技术-材料科学：硅酸盐

CiteScore

1.20

自引率

14.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.