N2O分子的N2-、O2-和空气增宽半宽和线混合参数及其温度依赖性

IF 1.9 3区物理与天体物理 Q2 OPTICS

Journal of Quantitative Spectroscopy & Radiative Transfer Pub Date : 2025-08-07 DOI:10.1016/j.jqsrt.2025.109628

Q. Ma , C. Boulet

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引用次数: 0

摘要

在195 ~ 350 K的温度范围内，利用改进的Robert Bonamy形式，研究了N2-、O2-和N2-、N2-和N2-在ν1波段的展宽和谱线混合参数。理论预测的半宽度与文献中的实验数据非常吻合，从而可靠地预测了温度指数n的旋转依赖性。由于我们的模型产生了完整的松弛矩阵W，它还可以计算Rozenkranz线混合参数。在与现有室温数据基本一致的基础上，分析了罗赞克兰兹参数的温度依赖性，并简要讨论了其物理来源。

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The N2-, O2-, and air-broadened halfwidths and line mixing parameters of the N2O molecule and their temperature dependences

Broadening and line mixing parameters for N₂-, O₂-, and air-broadened N₂O transitions in the ν₁ band are investigated over temperatures ranging of 195 to 350 K, using the Refined Robert Bonamy formalism. The theoretically predicted halfwidths show very good agreement with experimental data from the literature, leading to a reliable prediction of the rotational dependence of the temperature exponent N. Since our model yields the full relaxation matrix W, it also enables calculation of Rozenkranz line mixing parameters. Based on the reasonable agreement with available data at room temperature, the temperature dependence of the Rozenkranz parameters has been analyzed, and its physical origin is briefly discussed.

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来源期刊

Journal of Quantitative Spectroscopy & Radiative Transfer 物理-光谱学

CiteScore

5.30

自引率

21.70%

发文量

273

审稿时长

58 days

期刊介绍： Papers with the following subject areas are suitable for publication in the Journal of Quantitative Spectroscopy and Radiative Transfer: - Theoretical and experimental aspects of the spectra of atoms, molecules, ions, and plasmas. - Spectral lineshape studies including models and computational algorithms. - Atmospheric spectroscopy. - Theoretical and experimental aspects of light scattering. - Application of light scattering in particle characterization and remote sensing. - Application of light scattering in biological sciences and medicine. - Radiative transfer in absorbing, emitting, and scattering media. - Radiative transfer in stochastic media.