Chongzhen Du, Chuanzhen Huang, Hanlian Liu, Xinyao Cui, Shijie Li, Dun Liu, Zhen Wang, Longhua Xu, Shuiquan Huang
{"title":"两步热压烧结制备具有热障功能的Ti(C,N)基微层陶瓷刀具及表征","authors":"Chongzhen Du, Chuanzhen Huang, Hanlian Liu, Xinyao Cui, Shijie Li, Dun Liu, Zhen Wang, Longhua Xu, Shuiquan Huang","doi":"10.1016/j.jallcom.2025.182982","DOIUrl":null,"url":null,"abstract":"Ti(C,N)-based cermet tools are confronted with the issues of insufficient strength and low mechanical properties at high cutting temperatures. In order to break through the bottleneck of the high-temperature performance of cutting tools, based on the concept of integrated structure-function design, this study designed a micro-laminated structure and introduced a composite phase with a low thermal conductivity coefficient to construct a thermal barrier layer on the surface of Ti(C,N)-based materials. By adjusting the content of WC in the matrix layer and adopting a two-step hot-pressing sintering process, the synergistic enhancement of the mechanical properties of the surface and matrix layer materials were achieved. The Vickers hardness of TWAZ2 tool material was 19.90<!-- --> <!-- -->GPa, the fracture toughness was 9.45<!-- --> <!-- -->MPa·m<sup>1/2</sup>, and the flexural strength was 950.81<!-- --> <!-- -->MPa. It demonstrated excellent high-temperature hardness and wear resistance, maintaining a hardness of 12.23<!-- --> <!-- -->GPa at 1000 ℃. Furthermore, a method for quantitatively characterizing the thermal barrier efficiency of the thermal barrier layer was proposed. The results showed that the temperature and heat flux density of tool materials with thermal barrier function were all reduced under the same thermal load conditions. In the laminated structure with thermal barrier function, the thermal shielding characteristics of the surface layer and the heat dissipation mechanism of the matrix layer form a synergistic effect, which played a positive role in prolonging the service life of the cutting tool. This research provides a new insight into the design and preparation of new tool materials considering the thermal-mechanical coupling effect.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"36 1","pages":""},"PeriodicalIF":6.3000,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication and characterization of Ti(C,N)-based micro-laminated ceramic tool with thermal barrier function by two-step hot-pressing sintering process\",\"authors\":\"Chongzhen Du, Chuanzhen Huang, Hanlian Liu, Xinyao Cui, Shijie Li, Dun Liu, Zhen Wang, Longhua Xu, Shuiquan Huang\",\"doi\":\"10.1016/j.jallcom.2025.182982\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Ti(C,N)-based cermet tools are confronted with the issues of insufficient strength and low mechanical properties at high cutting temperatures. In order to break through the bottleneck of the high-temperature performance of cutting tools, based on the concept of integrated structure-function design, this study designed a micro-laminated structure and introduced a composite phase with a low thermal conductivity coefficient to construct a thermal barrier layer on the surface of Ti(C,N)-based materials. By adjusting the content of WC in the matrix layer and adopting a two-step hot-pressing sintering process, the synergistic enhancement of the mechanical properties of the surface and matrix layer materials were achieved. The Vickers hardness of TWAZ2 tool material was 19.90<!-- --> <!-- -->GPa, the fracture toughness was 9.45<!-- --> <!-- -->MPa·m<sup>1/2</sup>, and the flexural strength was 950.81<!-- --> <!-- -->MPa. It demonstrated excellent high-temperature hardness and wear resistance, maintaining a hardness of 12.23<!-- --> <!-- -->GPa at 1000 ℃. Furthermore, a method for quantitatively characterizing the thermal barrier efficiency of the thermal barrier layer was proposed. The results showed that the temperature and heat flux density of tool materials with thermal barrier function were all reduced under the same thermal load conditions. In the laminated structure with thermal barrier function, the thermal shielding characteristics of the surface layer and the heat dissipation mechanism of the matrix layer form a synergistic effect, which played a positive role in prolonging the service life of the cutting tool. This research provides a new insight into the design and preparation of new tool materials considering the thermal-mechanical coupling effect.\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"36 1\",\"pages\":\"\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-08-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jallcom.2025.182982\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jallcom.2025.182982","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Fabrication and characterization of Ti(C,N)-based micro-laminated ceramic tool with thermal barrier function by two-step hot-pressing sintering process
Ti(C,N)-based cermet tools are confronted with the issues of insufficient strength and low mechanical properties at high cutting temperatures. In order to break through the bottleneck of the high-temperature performance of cutting tools, based on the concept of integrated structure-function design, this study designed a micro-laminated structure and introduced a composite phase with a low thermal conductivity coefficient to construct a thermal barrier layer on the surface of Ti(C,N)-based materials. By adjusting the content of WC in the matrix layer and adopting a two-step hot-pressing sintering process, the synergistic enhancement of the mechanical properties of the surface and matrix layer materials were achieved. The Vickers hardness of TWAZ2 tool material was 19.90 GPa, the fracture toughness was 9.45 MPa·m1/2, and the flexural strength was 950.81 MPa. It demonstrated excellent high-temperature hardness and wear resistance, maintaining a hardness of 12.23 GPa at 1000 ℃. Furthermore, a method for quantitatively characterizing the thermal barrier efficiency of the thermal barrier layer was proposed. The results showed that the temperature and heat flux density of tool materials with thermal barrier function were all reduced under the same thermal load conditions. In the laminated structure with thermal barrier function, the thermal shielding characteristics of the surface layer and the heat dissipation mechanism of the matrix layer form a synergistic effect, which played a positive role in prolonging the service life of the cutting tool. This research provides a new insight into the design and preparation of new tool materials considering the thermal-mechanical coupling effect.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.