两步热压烧结制备具有热障功能的Ti(C,N)基微层陶瓷刀具及表征

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Chongzhen Du, Chuanzhen Huang, Hanlian Liu, Xinyao Cui, Shijie Li, Dun Liu, Zhen Wang, Longhua Xu, Shuiquan Huang
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引用次数: 0

摘要

Ti(C,N)基金属陶瓷刀具在高温下存在强度不足、力学性能低等问题。为了突破刀具高温性能的瓶颈,本研究基于结构-功能一体化设计的理念,设计了微层状结构,并引入了导热系数较低的复合相,在Ti(C,N)基材料表面构建热障层。通过调整基体层WC的含量,采用两步热压烧结工艺,实现了表面和基体层材料力学性能的协同增强。TWAZ2刀具材料的维氏硬度为19.90 GPa,断裂韧性为9.45 MPa·m1/2,抗弯强度为950.81 MPa。它具有优异的高温硬度和耐磨性,在1000℃时硬度保持在12.23 GPa。此外,还提出了一种定量表征热障层热障效率的方法。结果表明:在相同热负荷条件下,具有热障功能的刀具材料的温度和热流密度均有所降低;在具有热障功能的层合结构中,表层的热屏蔽特性与基体层的散热机制形成协同效应,对延长刀具的使用寿命起到了积极的作用。该研究为考虑热-力耦合效应的新型刀具材料的设计和制备提供了新的思路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fabrication and characterization of Ti(C,N)-based micro-laminated ceramic tool with thermal barrier function by two-step hot-pressing sintering process
Ti(C,N)-based cermet tools are confronted with the issues of insufficient strength and low mechanical properties at high cutting temperatures. In order to break through the bottleneck of the high-temperature performance of cutting tools, based on the concept of integrated structure-function design, this study designed a micro-laminated structure and introduced a composite phase with a low thermal conductivity coefficient to construct a thermal barrier layer on the surface of Ti(C,N)-based materials. By adjusting the content of WC in the matrix layer and adopting a two-step hot-pressing sintering process, the synergistic enhancement of the mechanical properties of the surface and matrix layer materials were achieved. The Vickers hardness of TWAZ2 tool material was 19.90 GPa, the fracture toughness was 9.45 MPa·m1/2, and the flexural strength was 950.81 MPa. It demonstrated excellent high-temperature hardness and wear resistance, maintaining a hardness of 12.23 GPa at 1000 ℃. Furthermore, a method for quantitatively characterizing the thermal barrier efficiency of the thermal barrier layer was proposed. The results showed that the temperature and heat flux density of tool materials with thermal barrier function were all reduced under the same thermal load conditions. In the laminated structure with thermal barrier function, the thermal shielding characteristics of the surface layer and the heat dissipation mechanism of the matrix layer form a synergistic effect, which played a positive role in prolonging the service life of the cutting tool. This research provides a new insight into the design and preparation of new tool materials considering the thermal-mechanical coupling effect.
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来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
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