二甲基（甲基硫）磺酸盐引发烯烃与CS2和胺的二硫代氨基化反应。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-08-05 DOI:10.1039/d5ob01043h

Sha Peng , Cheng-Mei Qi , Li-Mei Duan , Ding Luo , Lu-Can Cheng , Si-Si Tian , Li-Hua Yang , Long-Yong Xie

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引用次数: 0

摘要

在这项工作中，报告了一个简单实用的四组分反应，涉及烯烃，CS2，胺和三氟甲烷磺酸二甲基（甲基硫）磺酸铵（DMTSM）。该反应可以方便地合成各种s -烷基二硫代氨基甲酸酯，收率很高。温和的反应条件，现成的起始材料和操作简单，以及许多后期功能化的例子，使该方法对有机合成具有很高的吸引力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Dimethyl(methylthio)sulfonium salt triggered dithiocarbamation of alkenes with CS2 and amines

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Dimethyl(methylthio)sulfonium salt triggered dithiocarbamation of alkenes with CS2 and amines

In this work, a straightforward and practical four-component reaction involving alkenes, CS₂, amines, and dimethyl(methylthio)sulfonium trifluoromethanesulfonate (DMTSM) is reported. This reaction enables the convenient synthesis of various S-alkyl dithiocarbamates in good to excellent yields. The mild reaction conditions, readily available starting materials and operational simplicity, along with numerous examples of late-stage functionalization, render this method highly attractive for organic synthesis.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.