Chenxi Wang, Jiaming Zhang, Zemin Xu, Lin Tian, Guie Shi
{"title":"滇中碳酸盐岩腐化作用的物理触发机制","authors":"Chenxi Wang, Jiaming Zhang, Zemin Xu, Lin Tian, Guie Shi","doi":"10.1007/s12665-025-12460-5","DOIUrl":null,"url":null,"abstract":"<div><p>This study systematically investigates the physical saprolitization mechanism of carbonate rocks in central Yunnan, China. Physical weathering plays a dominant role, at least during the early to middle stages of saprolitization, based on comparative analyses of saprolite samples with varying weathering (powderization) degrees in terms of crystal morphology, chemical composition, and pore structure. Scanning electron microscopy and pore structure analysis reveal that the structural connections between crystal grains are progressively destroyed during the transformation from corestone to saprolite, a process highly consistent with fatigue failure characteristics. Following matrix suction experiments confirming that moisture fluctuations regularly alter suction within rocks, a theoretical analysis was introduced to further explore the triggering mechanism. Inspired by the one-dimensional spherical soil particle model, it is inferred that suction fluctuations accumulate at the grain scale to generate dynamic tensile stresses, providing a plausible source of dynamic loading responsible for fatigue failure. Field evidence further supports this mechanism: Saprolite tends to form near the bedrock–soil interface, as the soil helps maintain a variable-humidity condition around the bedrock. In the same region, saprolites near the surface exhibit a higher degree of powderization than those at depth, and greater powderization also occurs in areas with higher pore connectivity—both consistent with more active moisture migration. This study establishes a closed-loop mechanism linking variable humidity, moisture migration, dynamic loading, and structural degradation, and offers a new perspective on saprolitization beyond the traditional framework of chemical weathering.</p></div>","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"84 16","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Physical triggering mechanism of carbonatic saprolitization in the Central Yunnan, China\",\"authors\":\"Chenxi Wang, Jiaming Zhang, Zemin Xu, Lin Tian, Guie Shi\",\"doi\":\"10.1007/s12665-025-12460-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study systematically investigates the physical saprolitization mechanism of carbonate rocks in central Yunnan, China. Physical weathering plays a dominant role, at least during the early to middle stages of saprolitization, based on comparative analyses of saprolite samples with varying weathering (powderization) degrees in terms of crystal morphology, chemical composition, and pore structure. Scanning electron microscopy and pore structure analysis reveal that the structural connections between crystal grains are progressively destroyed during the transformation from corestone to saprolite, a process highly consistent with fatigue failure characteristics. Following matrix suction experiments confirming that moisture fluctuations regularly alter suction within rocks, a theoretical analysis was introduced to further explore the triggering mechanism. Inspired by the one-dimensional spherical soil particle model, it is inferred that suction fluctuations accumulate at the grain scale to generate dynamic tensile stresses, providing a plausible source of dynamic loading responsible for fatigue failure. Field evidence further supports this mechanism: Saprolite tends to form near the bedrock–soil interface, as the soil helps maintain a variable-humidity condition around the bedrock. In the same region, saprolites near the surface exhibit a higher degree of powderization than those at depth, and greater powderization also occurs in areas with higher pore connectivity—both consistent with more active moisture migration. This study establishes a closed-loop mechanism linking variable humidity, moisture migration, dynamic loading, and structural degradation, and offers a new perspective on saprolitization beyond the traditional framework of chemical weathering.</p></div>\",\"PeriodicalId\":542,\"journal\":{\"name\":\"Environmental Earth Sciences\",\"volume\":\"84 16\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Earth Sciences\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12665-025-12460-5\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Earth Sciences","FirstCategoryId":"93","ListUrlMain":"https://link.springer.com/article/10.1007/s12665-025-12460-5","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Physical triggering mechanism of carbonatic saprolitization in the Central Yunnan, China
This study systematically investigates the physical saprolitization mechanism of carbonate rocks in central Yunnan, China. Physical weathering plays a dominant role, at least during the early to middle stages of saprolitization, based on comparative analyses of saprolite samples with varying weathering (powderization) degrees in terms of crystal morphology, chemical composition, and pore structure. Scanning electron microscopy and pore structure analysis reveal that the structural connections between crystal grains are progressively destroyed during the transformation from corestone to saprolite, a process highly consistent with fatigue failure characteristics. Following matrix suction experiments confirming that moisture fluctuations regularly alter suction within rocks, a theoretical analysis was introduced to further explore the triggering mechanism. Inspired by the one-dimensional spherical soil particle model, it is inferred that suction fluctuations accumulate at the grain scale to generate dynamic tensile stresses, providing a plausible source of dynamic loading responsible for fatigue failure. Field evidence further supports this mechanism: Saprolite tends to form near the bedrock–soil interface, as the soil helps maintain a variable-humidity condition around the bedrock. In the same region, saprolites near the surface exhibit a higher degree of powderization than those at depth, and greater powderization also occurs in areas with higher pore connectivity—both consistent with more active moisture migration. This study establishes a closed-loop mechanism linking variable humidity, moisture migration, dynamic loading, and structural degradation, and offers a new perspective on saprolitization beyond the traditional framework of chemical weathering.
期刊介绍:
Environmental Earth Sciences is an international multidisciplinary journal concerned with all aspects of interaction between humans, natural resources, ecosystems, special climates or unique geographic zones, and the earth:
Water and soil contamination caused by waste management and disposal practices
Environmental problems associated with transportation by land, air, or water
Geological processes that may impact biosystems or humans
Man-made or naturally occurring geological or hydrological hazards
Environmental problems associated with the recovery of materials from the earth
Environmental problems caused by extraction of minerals, coal, and ores, as well as oil and gas, water and alternative energy sources
Environmental impacts of exploration and recultivation – Environmental impacts of hazardous materials
Management of environmental data and information in data banks and information systems
Dissemination of knowledge on techniques, methods, approaches and experiences to improve and remediate the environment
In pursuit of these topics, the geoscientific disciplines are invited to contribute their knowledge and experience. Major disciplines include: hydrogeology, hydrochemistry, geochemistry, geophysics, engineering geology, remediation science, natural resources management, environmental climatology and biota, environmental geography, soil science and geomicrobiology.