苯并恶嗪合成无溶剂技术、绿色催化及生物质资源策略的研究进展及应用

IF 5.1 3区工程技术 Q1 CHEMISTRY, APPLIED

Reactive & Functional Polymers Pub Date : 2025-08-05 DOI:10.1016/j.reactfunctpolym.2025.106434

Yu Luo, Liwu Zu, Shaobo Dong, Tianyu Lan, Lu Zhang, Wei Zhang, Jun Liu

{"title":"苯并恶嗪合成无溶剂技术、绿色催化及生物质资源策略的研究进展及应用","authors":"Yu Luo, Liwu Zu, Shaobo Dong, Tianyu Lan, Lu Zhang, Wei Zhang, Jun Liu","doi":"10.1016/j.reactfunctpolym.2025.106434","DOIUrl":null,"url":null,"abstract":"<div><div>Benzoxazine-based thermosetting polymers have emerged as a research hotspot in advanced material science, distinguished by their unique heterocyclic molecular architecture that synergistically integrates superior thermal resistance, tunable mechanical strength, and inherent molecular design flexibility. Recent developments in sustainable chemistry have catalyzed paradigm shifts in benzoxazine fabrication methodologies, particularly addressing the environmental concerns associated with traditional synthesis routes involving toxic phenolic derivatives and hazardous solvents. This review systematically summarizes the cutting-edge advancements in the eco-friendly synthesis of Bz, focusing on three pivotal strategies: solvent-free synthesis, high-efficiency catalytic systems, and biomass-derived feedstock utilization, while critically evaluating their transformative potential and limitations in functional material applications.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"216 ","pages":"Article 106434"},"PeriodicalIF":5.1000,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Research progress and application of solvent-free technology, green catalysis and biomass resource strategy for the synthesis of benzoxazine\",\"authors\":\"Yu Luo, Liwu Zu, Shaobo Dong, Tianyu Lan, Lu Zhang, Wei Zhang, Jun Liu\",\"doi\":\"10.1016/j.reactfunctpolym.2025.106434\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Benzoxazine-based thermosetting polymers have emerged as a research hotspot in advanced material science, distinguished by their unique heterocyclic molecular architecture that synergistically integrates superior thermal resistance, tunable mechanical strength, and inherent molecular design flexibility. Recent developments in sustainable chemistry have catalyzed paradigm shifts in benzoxazine fabrication methodologies, particularly addressing the environmental concerns associated with traditional synthesis routes involving toxic phenolic derivatives and hazardous solvents. This review systematically summarizes the cutting-edge advancements in the eco-friendly synthesis of Bz, focusing on three pivotal strategies: solvent-free synthesis, high-efficiency catalytic systems, and biomass-derived feedstock utilization, while critically evaluating their transformative potential and limitations in functional material applications.</div></div>\",\"PeriodicalId\":20916,\"journal\":{\"name\":\"Reactive & Functional Polymers\",\"volume\":\"216 \",\"pages\":\"Article 106434\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-08-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive & Functional Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S138151482500286X\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive & Functional Polymers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S138151482500286X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

摘要

基于苯并恶嗪的热固性聚合物以其独特的杂环分子结构协同集成了优异的耐热性、可调节的机械强度和固有的分子设计灵活性而成为先进材料科学的研究热点。可持续化学的最新发展促进了苯并恶嗪制造方法的范式转变，特别是解决了与涉及有毒酚衍生物和有害溶剂的传统合成路线相关的环境问题。本文系统总结了Bz生态合成的最新进展，重点介绍了三种关键策略：无溶剂合成、高效催化体系和生物质原料利用，同时批判性地评估了它们在功能材料应用中的变革潜力和局限性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Research progress and application of solvent-free technology, green catalysis and biomass resource strategy for the synthesis of benzoxazine

查看原文本刊更多论文

Research progress and application of solvent-free technology, green catalysis and biomass resource strategy for the synthesis of benzoxazine

Benzoxazine-based thermosetting polymers have emerged as a research hotspot in advanced material science, distinguished by their unique heterocyclic molecular architecture that synergistically integrates superior thermal resistance, tunable mechanical strength, and inherent molecular design flexibility. Recent developments in sustainable chemistry have catalyzed paradigm shifts in benzoxazine fabrication methodologies, particularly addressing the environmental concerns associated with traditional synthesis routes involving toxic phenolic derivatives and hazardous solvents. This review systematically summarizes the cutting-edge advancements in the eco-friendly synthesis of Bz, focusing on three pivotal strategies: solvent-free synthesis, high-efficiency catalytic systems, and biomass-derived feedstock utilization, while critically evaluating their transformative potential and limitations in functional material applications.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Reactive & Functional Polymers 工程技术-高分子科学

CiteScore

8.90

自引率

5.90%

发文量

259

审稿时长

27 days

期刊介绍： Reactive & Functional Polymers provides a forum to disseminate original ideas, concepts and developments in the science and technology of polymers with functional groups, which impart specific chemical reactivity or physical, chemical, structural, biological, and pharmacological functionality. The scope covers organic polymers, acting for instance as reagents, catalysts, templates, ion-exchangers, selective sorbents, chelating or antimicrobial agents, drug carriers, sensors, membranes, and hydrogels. This also includes reactive cross-linkable prepolymers and high-performance thermosetting polymers, natural or degradable polymers, conducting polymers, and porous polymers. Original research articles must contain thorough molecular and material characterization data on synthesis of the above polymers in combination with their applications. Applications include but are not limited to catalysis, water or effluent treatment, separations and recovery, electronics and information storage, energy conversion, encapsulation, or adhesion.