水合物在解离过程中的动态电性质:来自多物理场耦合模拟的新见解

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS
Yilun Zhang,  and , Xixi Lan*, 
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引用次数: 0

摘要

由于天然气水合物只有在低温高压条件下才稳定,在开采过程中,一旦条件发生变化,天然气水合物就会解离,由固态转化为气态,甲烷气体的大量释放会导致温室效应。表征水合物解离过程中的动态电学性质提出了基本挑战,特别是关于时间依赖机制。通过孔隙尺度的有限元模拟,结合热电场耦合,动态模拟海洋含水合物沉积物的相变过程。所构建的三维框架解释了解离过程中水合物的不同分布模式和饱和度水平。结果表明,电阻率随温度变化和水合物相变逐渐降低。根据热传导引起的温度变化,水合物解离过程可分为三个阶段。水合物相变过程中饱和度的变化影响电阻率变化的速度,但不改变电阻率变化的趋势。在不同的分布形态下,水合物解离随时间的变化趋势是相似的。该研究增强了对动态解耦条件下含水合物沉积物中耦合热电响应的认识,为了解相变含水合物沉积物的电性质提供了新的思路,在天然气水合物开发中具有潜在的应用价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Dynamic Electrical Properties of Hydrate during Dissociation: New Insights from Multiphysics Coupling Simulation

Dynamic Electrical Properties of Hydrate during Dissociation: New Insights from Multiphysics Coupling Simulation

Since natural gas hydrate is stable only under low-temperature and high-pressure conditions, it will dissociate and transform from a solid to gas state once conditions vary in the course of exploitation, and the massive release of methane gas will lead to the greenhouse effect. Characterizing the dynamic electrical properties during hydrate dissociation presents fundamental challenges, particularly with regard to time-dependent mechanisms. This study investigates marine hydrate-bearing sediments through pore-scale finite element modeling, coupling thermal and electrical fields to dynamically simulate phase transition processes. The constructed three-dimensional framework accounts for diverse hydrate distribution patterns and saturation levels during dissociation. The results show that resistivity decreases gradually with temperature changes and hydrate phase transition. According to the temperature change caused by heat conduction, the hydrate dissociation process can be divided into three stages. Moreover, the variation in saturation during the hydrate phase transition affects the speed of resistivity variation but does not change the trend of that. It is also found that the trend of hydrate dissociation with time is similar for different distribution morphologies. This study enhances the understanding of coupled thermoelectrical responses in hydrate-bearing sediments under dynamic dissociation conditions and provides insight into the electrical properties of hydrate-bearing sediments with phase transition and shows potential application value in the exploitation of natural gas hydrate.

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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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