极化带电卟啉的离子配对组合。

IF 3.7 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-08-07 DOI:10.1002/chem.202502225

Ryo Kitayama, Prof. Yohei Haketa, Yuto Maruyama, Masaki Fujita, Dr. Hiroki Tanaka, Dr. Hiroki Horita, Prof. Hiromitsu Maeda

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引用次数: 0

摘要

合成了一种含有5,10-五氟苯基的卟啉配合物，作为偶极π电子阳离子。π-电子阳离子与阴离子结合，包括体积较大的硼酸盐阴离子和平面π-电子阴离子。偶极π-电子阳离子形成了基于反平行堆叠结构的晶体态离子对组合，并通过离子间偶极-偶极相互作用得到稳定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ion-Pairing Assemblies of Polarized Charged Porphyrin

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Ion-Pairing Assemblies of Polarized Charged Porphyrin

A porphyrin Au^III complex comprising 5,10-penatafluorophenyl units was synthesized as a dipolar π-electronic cation. The π-electronic cation was combined with anions, including a bulky borate anion and planar π-electronic anions. The dipolar π-electronic cation formed crystal-state ion-pairing assemblies based on antiparallel stacking structures, which were stabilized by interionic dipole–dipole interactions.

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来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.