1,2-二氯乙烷在Co-N4上电化学还原的周边环境效应

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-30 DOI:10.1039/d5cc03139g

Tengfei Long , Junfeng Zeng , Jiawei Hu , Hongli Zhu , Shiguo Zhang , Wenpeng Ni

引用次数: 0

摘要

对于1,2-二氯乙烷（DCE）在单金属位点上的电化学二氯化，远端非金属物质的作用仍未得到充分的研究。外围共轭结构和氮原子加速了* ch2ch2cl向* ch2ch2的转化和乙烯的脱附。CoPc的fe乙烯含量为95.19±0.02%，je乙烯含量提高了75.8倍。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Peripheral environmental effect for the electrochemical reduction of 1,2-dichloroethane over a single Co–N4 site

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Peripheral environmental effect for the electrochemical reduction of 1,2-dichloroethane over a single Co–N4 site

The role of remote nonmetallic species remains underexplored for 1,2-dichloroethane (DCE) electrochemical dechlorination over single-metal sites. We demonstrated that a peripheral conjugated structure and nitrogen atoms accelerate the transformation of *CH₂CH₂Cl to *CH₂CH₂ and ethylene desorption. CoPc achieved an FE_ethylene of 95.19 ± 0.02% and a 75.8-fold increase in J_ethylene.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.