极端大气环境中带电、极化粒子的静电聚集。

IF 2.8 2区 化学 Q3 CHEMISTRY, PHYSICAL
Cameron P. Reeve, Connor Williamson, Evan Shelton, Anthony J. Stace and Elena Besley*, 
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引用次数: 0

摘要

极端的大气环境通常以高温和高密度的带电、极化粒子为特征。本研究调查了两种截然不同的极端环境,火山灰羽流和金星大气,其中粒子极化的影响在驱动静电聚集中起着关键作用,特别是在小间距处通过类电荷吸引,这通常被传统模型所忽视。在这些条件下,与库仑定律和硬球极限预测相比,考虑复杂极化效应可将碰撞效率和碰撞截面的估计提高25%,并将聚集临界速度值降低30%。这些见解对更广泛的工业、大气和天体物理背景下的带电粒子动力学建模具有广泛的意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrostatic Aggregation of Charged, Polarizable Particles in Extreme Atmospheric Environments

Extreme atmospheric environments are often characterized by scorching temperatures and high densities of charged, polarizable particles. This study investigates two distinctly different extreme environments, volcanic ash plumes and the Venusian atmosphere, where the influence of particle polarization plays a pivotal role in driving electrostatic aggregation, particularly through like-charge attraction at small separations, which is often neglected by conventional models. In these conditions, accounting for complex polarization effects increases the estimation of collision efficiency and collision cross section by up to 25% as well as reduces the value of the velocity critical for aggregation by up to 30%, as compared to predictions by Coulomb’s Law and the hard-sphere limit. These insights have wide-ranging implications for modeling charged particle dynamics in broader industrial, atmospheric, and astrophysical contexts.

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来源期刊
The Journal of Physical Chemistry A
The Journal of Physical Chemistry A 化学-物理:原子、分子和化学物理
CiteScore
5.20
自引率
10.30%
发文量
922
审稿时长
1.3 months
期刊介绍: The Journal of Physical Chemistry A is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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