用于可穿戴设备和手写指纹识别的DLP 3d打印锥形金字塔水凝胶传感器。

IF 8.2 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Dake Huang, Jian Qi*, Shuo Gao, Lukui Yin, Houjun Qi and Shuxian Zheng*, 
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引用次数: 0

摘要

柔性水凝胶传感器由于其优异的柔韧性和生物相容性,在可穿戴应用中引起了广泛的关注。然而,长期稳定性不足、灵敏度范围有限以及依赖传统模具进行微结构设计等挑战迫切需要解决。本研究通过数字光处理(DLP) 3D打印技术,突破现有技术瓶颈,构建了具有多层锥形金字塔微结构的双离子导电水凝胶传感器。采用负载Mg2+/Na+离子体系的丙烯酰胺(AM)-聚乙二醇二丙烯酸酯(PEGDA)双网络基质,结合30 wt %的甘油改性,使水凝胶的保水率提高到90%以上,解决了传统水凝胶中离子浓度波动造成的失水问题。对比6种单一微观结构的仿真结果表明,圆锥金字塔结构依靠逐步压缩变形机制(三层结构依次接触电极层),在0-0.8 kPa压力范围内获得了0.544 kPa-1的灵敏度,比传统金字塔结构提高了78%。它的特点是响应时间为30 ms,恢复时间为40 ms,使用联合压力轨迹特征的信号衰减为2.5%。DLP打印的高分辨率特性(精度7.8 μm,尺寸误差<9.13%)突破了传统模具对复杂结构的限制,为快速微结构成型提供了新的范例。与现有的柔性传感器相比,本研究在灵敏度和稳定性的协同性能上有了显著的提高。本文提出的锥形金字塔结构设计原理和双离子调节策略为解决复杂环境下传感器性能下降问题提供了一种通用的解决方案。“手写体指纹”技术在身份认证、医疗监控、智能防伪等领域显示出广阔的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

DLP 3D-Printed Conic-Pyramid Hydrogel Sensor for Wearable Devices and Handwritten Fingerprint Recognition

DLP 3D-Printed Conic-Pyramid Hydrogel Sensor for Wearable Devices and Handwritten Fingerprint Recognition

Flexible hydrogel sensors have attracted significant attention in wearable applications due to their excellent flexibility and biocompatibility. However, challenges such as insufficient long-term stability, limited sensitivity range, and reliance on traditional molds for microstructure design urgently need to be addressed. This study constructs a dual-ion conductive hydrogel sensor with multilevel conic-pyramid microstructures via Digital Light Processing (DLP) 3D printing, breaking through existing technical bottlenecks. Using an acrylamide (AM)-poly(ethylene glycol) diacrylate (PEGDA) double-network matrix loaded with a Mg2+/Na+ ion system, combined with 30 wt % glycerol modification, the water retention rate of the hydrogel is increased to over 90%, solving the ion concentration fluctuation problem in traditional hydrogels caused by water loss. Simulations comparing six single microstructures show that the conic-pyramid structure, relying on a stepwise compression deformation mechanism (three-level structures sequentially contacting the electrode layer), achieves a sensitivity of 0.544 kPa–1 in the 0–0.8 kPa pressure range, representing a 78% improvement over traditional pyramid structures. It features a response time of 30 ms, a recovery time of 40 ms, and a signal attenuation <4% after 10,000 cycle tests, with stability improved by 56% compared to single Na+ systems. The sensor enables real-time monitoring of finger joint bending (55% resistance variation at 90° bending) and wrist movements (64% resistance variation) through a 9 × 9 orthogonal electrode grid and achieves “handwriting fingerprint” recognition for different writers (signal differences >2.5%) using combined pressure-trajectory features. The high-resolution characteristics (7.8 μm precision, size error <9.13%) of DLP printing breaks through the limitations of traditional molds for complex structures, providing a new paradigm for rapid microstructure prototyping. Compared with existing flexible sensors, this study demonstrates significant improvements in the synergistic performance of sensitivity and stability. The conic-pyramid structure design principle and dual-ion regulation strategy proposed herein offer a universal solution to address sensor performance degradation in complex environments. The “handwriting fingerprint” technology shows broad application potential in identity authentication, medical monitoring, and intelligent anticounterfeiting fields.

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来源期刊
ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces 工程技术-材料科学:综合
CiteScore
16.00
自引率
6.30%
发文量
4978
审稿时长
1.8 months
期刊介绍: ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.
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