过量氟离子插入/提取实现地球丰富阴极的超高容量（能源材料，29/2025）

IF 26 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Advanced Energy Materials Pub Date : 2025-08-05 DOI:10.1002/aenm.70005

Yanchang Wang, Kentaro Yamamoto, Yuki Sakaguchi, Jun Miyawaki, Toshiyuki Matsunaga, Datong Zhang, Hisao Kiuchi, Zulai Cao, Koji Nakanishi, Toshiki Watanabe, Neha Thakur, Mukesh Kumar, Hidenori Miki, Hideki Iba, Kazuhiko Maeda, Yoshihisa Harada, Hiroshi Kageyama, Yoshiharu Uchimoto

{"title":"过量氟离子插入/提取实现地球丰富阴极的超高容量（能源材料，29/2025）","authors":"Yanchang Wang, Kentaro Yamamoto, Yuki Sakaguchi, Jun Miyawaki, Toshiyuki Matsunaga, Datong Zhang, Hisao Kiuchi, Zulai Cao, Koji Nakanishi, Toshiki Watanabe, Neha Thakur, Mukesh Kumar, Hidenori Miki, Hideki Iba, Kazuhiko Maeda, Yoshihisa Harada, Hiroshi Kageyama, Yoshiharu Uchimoto","doi":"10.1002/aenm.70005","DOIUrl":null,"url":null,"abstract":"Fluoride-Ion BatteriesIn article number 2406131, Kentaro Yamamoto and co-workers develop oxyfluoride cathodes SrFeO2Fx and Sr-substituted CaFeO2Fx, which deliver high capacities by (de)intercalating excess F− using Fe2+/Fe3+ redox and oxygen redox (O–O bond formation). The Ca0.8Sr0.2FeO2Fx among them has an extreme large reversible capacity of 580 mAh g−1.\n\n <figure>\n <div><picture>\n <source></source></picture>\n </div>\n </figure>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 29","pages":""},"PeriodicalIF":26.0000,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.70005","citationCount":"0","resultStr":"{\"title\":\"Ultra-High-Capacity of Earth-Abundant Cathodes Enabled by Excess Fluoride-Ion Insertion/Extraction (Adv. Energy Mater. 29/2025)\",\"authors\":\"Yanchang Wang, Kentaro Yamamoto, Yuki Sakaguchi, Jun Miyawaki, Toshiyuki Matsunaga, Datong Zhang, Hisao Kiuchi, Zulai Cao, Koji Nakanishi, Toshiki Watanabe, Neha Thakur, Mukesh Kumar, Hidenori Miki, Hideki Iba, Kazuhiko Maeda, Yoshihisa Harada, Hiroshi Kageyama, Yoshiharu Uchimoto\",\"doi\":\"10.1002/aenm.70005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fluoride-Ion BatteriesIn article number 2406131, Kentaro Yamamoto and co-workers develop oxyfluoride cathodes SrFeO2Fx and Sr-substituted CaFeO2Fx, which deliver high capacities by (de)intercalating excess F− using Fe2+/Fe3+ redox and oxygen redox (O–O bond formation). The Ca0.8Sr0.2FeO2Fx among them has an extreme large reversible capacity of 580 mAh g−1.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture>\\n </div>\\n </figure>\",\"PeriodicalId\":111,\"journal\":{\"name\":\"Advanced Energy Materials\",\"volume\":\"15 29\",\"pages\":\"\"},\"PeriodicalIF\":26.0000,\"publicationDate\":\"2025-08-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.70005\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Energy Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aenm.70005\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Energy Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aenm.70005","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

在文章编号2406131中，Kentaro Yamamoto及其同事开发了含氟氧离子阴极SrFeO2Fx和sr取代的CaFeO2Fx，它们通过使用Fe2+/Fe3+氧化还原和氧氧化还原（O-O键形成）（去）插入过量的F -来提供高容量。其中Ca0.8Sr0.2FeO2Fx具有580 mAh g−1的超大可逆容量。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ultra-High-Capacity of Earth-Abundant Cathodes Enabled by Excess Fluoride-Ion Insertion/Extraction (Adv. Energy Mater. 29/2025)

查看原文本刊更多论文

Ultra-High-Capacity of Earth-Abundant Cathodes Enabled by Excess Fluoride-Ion Insertion/Extraction (Adv. Energy Mater. 29/2025)

Fluoride-Ion Batteries

In article number 2406131, Kentaro Yamamoto and co-workers develop oxyfluoride cathodes SrFeO₂F_x and Sr-substituted CaFeO₂F_x, which deliver high capacities by (de)intercalating excess F⁻ using Fe²⁺/Fe³⁺ redox and oxygen redox (O–O bond formation). The Ca_0.8Sr_0.2FeO₂F_x among them has an extreme large reversible capacity of 580 mAh g⁻¹.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS

CiteScore

41.90

自引率

4.00%

发文量

889

审稿时长

1.4 months

期刊介绍： Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.