{"title":"纳米结构生物复合材料:协同高岭土-几丁质磁体对水中镉(II)的可持续缓解","authors":"Elaheh NaserNasir, Hossein Parvaresh, Fatemeh S. Mohseni-Shahri, Farid Moeinpour, Mohsen Dehghani Ghanatghestani","doi":"10.1002/aoc.70288","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>A novel functionalized halloysite-nanochitin magnetic biocomposite, NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin, was synthesized to effectively remove Cd (II) ions from aqueous media. The morphology and structure of the nanoadsorbent were analyzed using TEM, SEM, XRD, FT-IR, BET, EDS, and VSM. The adsorption studies demonstrated a peak Cd (II) adsorption capacity of 400.00 mg/g under conditions of 25°C, pH 6, using 0.05 g/100 mL of NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin, with equilibrium achieved within just 10 min. Adsorption kinetics follow a pseudo-second-order model, and the isothermal data corresponded with the Langmuir model, suggesting monolayer adsorption on the adsorbent surface and a chemically controlled rate-determining step. The thermodynamic analysis showed that the uptake process is both spontaneous and exothermic (<i>ΔH</i> = −511.028 kJ/mol, <i>ΔG</i> = −32.78 kJ/mol). Remarkably, the adsorbent maintained high uptake and release effectiveness even after four cycles, with the primary mechanism of Cd (II) removal attributed to chelation through oxygen (O) and nitrogen (N) atoms. These results demonstrate that NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin is a highly efficient and recyclable sorbent for removing Cd (II) ions from water, with significant practical applicability.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 9","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nanoarchitectured Biocomposites: Synergistic Halloysite-Chitin Magnets for Sustainable Cadmium (II) Mitigation in Water\",\"authors\":\"Elaheh NaserNasir, Hossein Parvaresh, Fatemeh S. Mohseni-Shahri, Farid Moeinpour, Mohsen Dehghani Ghanatghestani\",\"doi\":\"10.1002/aoc.70288\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>A novel functionalized halloysite-nanochitin magnetic biocomposite, NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin, was synthesized to effectively remove Cd (II) ions from aqueous media. The morphology and structure of the nanoadsorbent were analyzed using TEM, SEM, XRD, FT-IR, BET, EDS, and VSM. The adsorption studies demonstrated a peak Cd (II) adsorption capacity of 400.00 mg/g under conditions of 25°C, pH 6, using 0.05 g/100 mL of NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin, with equilibrium achieved within just 10 min. Adsorption kinetics follow a pseudo-second-order model, and the isothermal data corresponded with the Langmuir model, suggesting monolayer adsorption on the adsorbent surface and a chemically controlled rate-determining step. The thermodynamic analysis showed that the uptake process is both spontaneous and exothermic (<i>ΔH</i> = −511.028 kJ/mol, <i>ΔG</i> = −32.78 kJ/mol). Remarkably, the adsorbent maintained high uptake and release effectiveness even after four cycles, with the primary mechanism of Cd (II) removal attributed to chelation through oxygen (O) and nitrogen (N) atoms. These results demonstrate that NiFe<sub>2</sub>O<sub>4</sub>-HNTs-chitin is a highly efficient and recyclable sorbent for removing Cd (II) ions from water, with significant practical applicability.</p>\\n </div>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"39 9\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-08-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70288\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70288","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Nanoarchitectured Biocomposites: Synergistic Halloysite-Chitin Magnets for Sustainable Cadmium (II) Mitigation in Water
A novel functionalized halloysite-nanochitin magnetic biocomposite, NiFe2O4-HNTs-chitin, was synthesized to effectively remove Cd (II) ions from aqueous media. The morphology and structure of the nanoadsorbent were analyzed using TEM, SEM, XRD, FT-IR, BET, EDS, and VSM. The adsorption studies demonstrated a peak Cd (II) adsorption capacity of 400.00 mg/g under conditions of 25°C, pH 6, using 0.05 g/100 mL of NiFe2O4-HNTs-chitin, with equilibrium achieved within just 10 min. Adsorption kinetics follow a pseudo-second-order model, and the isothermal data corresponded with the Langmuir model, suggesting monolayer adsorption on the adsorbent surface and a chemically controlled rate-determining step. The thermodynamic analysis showed that the uptake process is both spontaneous and exothermic (ΔH = −511.028 kJ/mol, ΔG = −32.78 kJ/mol). Remarkably, the adsorbent maintained high uptake and release effectiveness even after four cycles, with the primary mechanism of Cd (II) removal attributed to chelation through oxygen (O) and nitrogen (N) atoms. These results demonstrate that NiFe2O4-HNTs-chitin is a highly efficient and recyclable sorbent for removing Cd (II) ions from water, with significant practical applicability.
期刊介绍:
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.