具有电流收集通孔电极的柔性钙钛矿太阳能电池

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2025-07-01 DOI:10.1002/solr.202500317
Hayato Okawa, Yuya Momose, Naoki Suyama, Ryousuke Ishikawa, Makoto Konagai
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引用次数: 0

摘要

钙钛矿太阳能电池(PSCs)由于其高效率和大规模应用的潜力而获得了相当大的关注,特别是在工业屋顶和建筑集成光伏发电中实施的柔性衬底。本文提出了一种采用聚酰亚胺(PI)薄膜制成的具有通孔集流结构的柔性psc。通过对PI薄膜进行精密冲压和优化除湿处理,成功制备出转换效率为12.3%、短路电流密度接近18 mA/cm2的钙钛矿电池。然而,孔边缘的薄膜厚度会影响性能,特别是填充系数,这是一个主要的挑战。此外,还讨论了激光刻划过程中引起的降解和水分渗透问题,并提出了提高薄膜覆盖率和减少泄漏电流的解决方案。研究结果表明,通孔结构可以提高柔性psc的卷对卷生产,在光伏系统中具有相当大的大规模应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Flexible Perovskite Solar Cells with Current Collection Through-Hole Electrodes

Flexible Perovskite Solar Cells with Current Collection Through-Hole Electrodes

Perovskite solar cells (PSCs) have gained considerable attention owing to their high efficiency and potential for large-scale applications, particularly for flexible substrates that are implemented in industrial roofing and building-integrated photovoltaics. In this article, flexible PSCs with a through-hole current-collection structure using polyimide (PI) films are proposed. Perovskite cells with a conversion efficiency of 12.3% and a short-circuit current density of nearly 18 mA/cm2 are successfully fabricated through the precise punching of the PI films and optimization of the dehumidification treatment. However, the film thickness at the hole edges affects the performance, particularly the fill factor, which is a major challenge. The laser scribing processes are also addressed, which cause degradation and issues with moisture penetration, and solutions for improving the film coverage and reducing leakage currents are proposed. The findings indicate that through-hole structures can enhance the roll-to-roll production of flexible PSCs, presenting considerable potential for large-scale applications in photovoltaic systems.

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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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