{"title":"基于石墨烯和MXenes的铅、镉和汞电化学传感研究进展","authors":"Khursheed Ahmad, Tae Hwan Oh","doi":"10.1016/j.talanta.2025.128671","DOIUrl":null,"url":null,"abstract":"<div><div>This review article presents the progress in the graphene and MXene based materials for the electrochemical detection of heavy metal ions (HMIs), including cadmium (Cd<sup>2+</sup>), lead (Pb<sup>2+</sup>), and mercury (Hg<sup>2+</sup>). This is well understood that these ions are highly toxic metals pollute the water and affect the human life and aquatic system. rGO as well as. MXenes are highly conductive materials with exceptional electrochemical properties, making them an ideal choice for electrochemical sensing applications. This review article provides an updated overview of reduced graphene oxide (rGO), graphene oxide (GO), and MXene-based hybrid composites for the detection of Cd<sup>2+</sup>, Hg<sup>2+</sup>, and Pb<sup>2+</sup> ions. We believe this scientific literature will serve as a valuable resource for electrochemists, offering insights into recent advancements in graphene and MXene-based electrode modifiers. These materials enable the selective, sensitive, and stable electrochemical determination of toxic heavy metal ions.</div></div>","PeriodicalId":435,"journal":{"name":"Talanta","volume":"297 ","pages":"Article 128671"},"PeriodicalIF":6.1000,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Progress in electrochemical sensing of lead, cadmium and mercury based on graphene and MXenes\",\"authors\":\"Khursheed Ahmad, Tae Hwan Oh\",\"doi\":\"10.1016/j.talanta.2025.128671\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This review article presents the progress in the graphene and MXene based materials for the electrochemical detection of heavy metal ions (HMIs), including cadmium (Cd<sup>2+</sup>), lead (Pb<sup>2+</sup>), and mercury (Hg<sup>2+</sup>). This is well understood that these ions are highly toxic metals pollute the water and affect the human life and aquatic system. rGO as well as. MXenes are highly conductive materials with exceptional electrochemical properties, making them an ideal choice for electrochemical sensing applications. This review article provides an updated overview of reduced graphene oxide (rGO), graphene oxide (GO), and MXene-based hybrid composites for the detection of Cd<sup>2+</sup>, Hg<sup>2+</sup>, and Pb<sup>2+</sup> ions. We believe this scientific literature will serve as a valuable resource for electrochemists, offering insights into recent advancements in graphene and MXene-based electrode modifiers. These materials enable the selective, sensitive, and stable electrochemical determination of toxic heavy metal ions.</div></div>\",\"PeriodicalId\":435,\"journal\":{\"name\":\"Talanta\",\"volume\":\"297 \",\"pages\":\"Article 128671\"},\"PeriodicalIF\":6.1000,\"publicationDate\":\"2025-08-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Talanta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0039914025011622\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Talanta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0039914025011622","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Progress in electrochemical sensing of lead, cadmium and mercury based on graphene and MXenes
This review article presents the progress in the graphene and MXene based materials for the electrochemical detection of heavy metal ions (HMIs), including cadmium (Cd2+), lead (Pb2+), and mercury (Hg2+). This is well understood that these ions are highly toxic metals pollute the water and affect the human life and aquatic system. rGO as well as. MXenes are highly conductive materials with exceptional electrochemical properties, making them an ideal choice for electrochemical sensing applications. This review article provides an updated overview of reduced graphene oxide (rGO), graphene oxide (GO), and MXene-based hybrid composites for the detection of Cd2+, Hg2+, and Pb2+ ions. We believe this scientific literature will serve as a valuable resource for electrochemists, offering insights into recent advancements in graphene and MXene-based electrode modifiers. These materials enable the selective, sensitive, and stable electrochemical determination of toxic heavy metal ions.
期刊介绍:
Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome.
Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.