{"title":"多金属氧酸盐介导的三明治结构介孔自组装polymer@rGO用于高性能锌碘水电池。","authors":"Wenyang Lu, Lebing Liu, Weibo Gong, Hengyue Xu, FengYang Xie, Xingrui Ji, Tingting Zhang, Shaohua Liu, Facai Wei, Chunxian Guo","doi":"10.1039/d5cc03153b","DOIUrl":null,"url":null,"abstract":"<p><p>Here, a polyoxometalate (POM)-mediated confined self-assembly strategy is reported to fabricate sandwich-structured mesoporous polymer@reduced graphene oxide (rGO) nanosheets that synergistically integrate conductive rGO, POM, and polymer networks, enhancing the iodine immobilization and kinetics in Zn-I<sub>2</sub> batteries and thus achieving high capacity (225 mAh g<sup>-1</sup>) and stability (84.5% retention after 3000 cycles).</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polyoxometalate-mediated confined self-assembly of sandwich-structured mesoporous polymer@rGO for high-performance aqueous zinc-iodine batteries.\",\"authors\":\"Wenyang Lu, Lebing Liu, Weibo Gong, Hengyue Xu, FengYang Xie, Xingrui Ji, Tingting Zhang, Shaohua Liu, Facai Wei, Chunxian Guo\",\"doi\":\"10.1039/d5cc03153b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Here, a polyoxometalate (POM)-mediated confined self-assembly strategy is reported to fabricate sandwich-structured mesoporous polymer@reduced graphene oxide (rGO) nanosheets that synergistically integrate conductive rGO, POM, and polymer networks, enhancing the iodine immobilization and kinetics in Zn-I<sub>2</sub> batteries and thus achieving high capacity (225 mAh g<sup>-1</sup>) and stability (84.5% retention after 3000 cycles).</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc03153b\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc03153b","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
本文报道了一种多金属氧酸盐(POM)介导的限制性自组装策略,制备了三明治结构的介孔氧化石墨烯(rGO)纳米片polymer@reduced,该纳米片协同整合了导电的rGO、POM和聚合物网络,增强了锌- i2电池中的碘固定化和动力学,从而实现了高容量(225 mAh g-1)和稳定性(3000次循环后保持率为84.5%)。
Polyoxometalate-mediated confined self-assembly of sandwich-structured mesoporous polymer@rGO for high-performance aqueous zinc-iodine batteries.
Here, a polyoxometalate (POM)-mediated confined self-assembly strategy is reported to fabricate sandwich-structured mesoporous polymer@reduced graphene oxide (rGO) nanosheets that synergistically integrate conductive rGO, POM, and polymer networks, enhancing the iodine immobilization and kinetics in Zn-I2 batteries and thus achieving high capacity (225 mAh g-1) and stability (84.5% retention after 3000 cycles).
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.