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ZIF-62的玻璃化过渡致发光

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Chemical Communications Pub Date : 2025-07-24 DOI:10.1039/d5cc01504a
Shuaihua Yu , Haitao Hu , Yichao Lin , Wen Yang , Ziqi Tian
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引用次数: 0

摘要

我们报道了ZIF-62玻璃在玻璃化转变时表现出增强的发光，与有序配体排列引起的晶体相荧光猝灭形成对比。理论模拟揭示了玻璃态的特定构型，且发射增强，实验证实了这一点。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Glass transition-induced luminescence in ZIF-62

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Glass transition-induced luminescence in ZIF-62
We reported that ZIF-62 glass exhibits enhanced luminescence upon glass transition, contrasting with the crystalline phase fluorescence quenching caused by ordered ligand arrangement. Theoretical simulations combining ab initio molecular dynamics and quantum mechanical calculations reveal specific configurations in the glassy state with intensified emission, which are corroborated by experiments.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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