二芳基碘鎓盐光氧化还原催化异硝基芳化制苯酰胺。

IF 2.1 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2025-07-21 eCollection Date: 2025-01-01 DOI:10.3762/bjoc.21.110

Nadezhda M Metalnikova, Nikita S Antonkin, Tuan K Nguyen, Natalia S Soldatova, Alexander V Nyuchev, Mikhail A Kinzhalov, Pavel S Postnikov

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引用次数: 0

摘要

首次提出了在光氧化还原条件下二芳基碘鎓盐对异硝基的芳基化反应。建议的程序允许在温和条件下使用对称和不对称二芳基碘鎓盐制备范围广泛的苯酰胺。研究了反应的机理和芳基转移的选择性（在不对称碘盐的情况下）。

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Photoredox-catalyzed arylation of isonitriles by diaryliodonium salts towards benzamides.

The arylation of isonitriles by diaryliodonium salts under photoredox conditions has been proposed for the first time. The suggested procedure allows preparing a broad range of benzamides using both symmetric and unsymmetric diaryliodonium salts under mild conditions. A plausible mechanism for the reaction and the selectivity of aryl transfer (in case of unsymmetrical iodonium salts) were studied.

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.