报废风力涡轮机叶片作为一种资源:热解和燃烧的比较研究

IF 6.2 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Sibel Başakçılardan Kabakcı , Ayşe Şenlik
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引用次数: 0

摘要

向低碳经济的转型加速了风能的安装。然而,由于废弃风力涡轮机叶片的复合性质和法规的限制,其管理仍然是一个挑战。本研究探讨了通过热解和燃烧对WTBs进行热化学回收,重点研究了气态排放、热解油、焦炭形态和灰分。wtb表现出低碳含量(29.5 wt%),热值为12 MJ/kg,高灰分含量(58 wt%),满足水泥生产的最低燃料门槛,但不符合EN 15359标准。热解测试结果表明,其分解行为(t set: 348℃,Tpeak: 390℃,Toffset:421℃),转化率为39.3 %。TG-FTIR分析鉴定出醇类、酯类、酚类和羰基,关键挥发物在366-417°C释放。热解油(C6-C40,以C15为主)富含双酚A衍生物,适于树脂生产。焦炭,主要是玻璃纤维,表现出低碳含量,使其适合作为混凝土或聚合物添加剂。燃烧试验表明,平均着火温度为276℃,燃尽温度为686.5℃,可燃性指标中等。二氧化碳排放量在421至572°C之间达到峰值。灰分形态显示玻璃纤维被松散粘附的灰分包围。这些发现支持WTB增值,促进能源和材料回收,同时解决环境问题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
End-of-life wind turbine blades as a resource: A comparative study of pyrolysis and combustion
The transition to a low-carbon economy has accelerated wind energy installations. However, managing waste wind turbine blades (WTBs) remains a challenge due to their composite nature and limited regulations. This study explores the thermochemical recovery of WTBs via pyrolysis and combustion, focusing on gaseous emissions, pyrolysis oil, pyrochar morphology and ash. WTBs exhibit low carbon content (29.5 wt%), a heating value of 12 MJ/kg, and high ash content (58 wt%), meeting the minimum fuel threshold for cement production but not EN 15359 standards. Pyrolysis tests revealed decomposition behavior (Tonset: 348 °C, Tpeak: 390 °C, Toffset:421 °C) with a 39.3 % conversion rate. TG-FTIR analysis identified alcohols, esters, phenolics, and carbonyl groups, with key volatiles released at 366–417 °C. Pyrolysis oil (C6-C40, dominated by C15) was rich in Bisphenol A derivatives, suitable for resin production. Pyrochar, primarily glass fiber, exhibited low carbon content, making it suitable as a concrete or polymer additive. Combustion tests showed a mean ignition temperature of 276 °C, burnout at 686.5 °C, and moderate combustibility index. CO2 emissions peaked between 421 and 572 °C. Ash morphology revealed glass fibers surrounded by loosely adherent ash. These findings support WTB valorization, promoting energy and material recovery while addressing environmental concerns.
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来源期刊
CiteScore
9.10
自引率
11.70%
发文量
340
审稿时长
44 days
期刊介绍: The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.
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