{"title":"报废风力涡轮机叶片作为一种资源:热解和燃烧的比较研究","authors":"Sibel Başakçılardan Kabakcı , Ayşe Şenlik","doi":"10.1016/j.jaap.2025.107308","DOIUrl":null,"url":null,"abstract":"<div><div>The transition to a low-carbon economy has accelerated wind energy installations. However, managing waste wind turbine blades (WTBs) remains a challenge due to their composite nature and limited regulations. This study explores the thermochemical recovery of WTBs via pyrolysis and combustion, focusing on gaseous emissions, pyrolysis oil, pyrochar morphology and ash. WTBs exhibit low carbon content (29.5 wt%), a heating value of 12 MJ/kg, and high ash content (58 wt%), meeting the minimum fuel threshold for cement production but not EN 15359 standards. Pyrolysis tests revealed decomposition behavior (T<sub>onset</sub>: 348 °C, T<sub>peak</sub>: 390 °C, T<sub>offset</sub>:421 °C) with a 39.3 % conversion rate. TG-FTIR analysis identified alcohols, esters, phenolics, and carbonyl groups, with key volatiles released at 366–417 °C. Pyrolysis oil (C6-C40, dominated by C15) was rich in Bisphenol A derivatives, suitable for resin production. Pyrochar, primarily glass fiber, exhibited low carbon content, making it suitable as a concrete or polymer additive. Combustion tests showed a mean ignition temperature of 276 °C, burnout at 686.5 °C, and moderate combustibility index. CO<sub>2</sub> emissions peaked between 421 and 572 °C. Ash morphology revealed glass fibers surrounded by loosely adherent ash. These findings support WTB valorization, promoting energy and material recovery while addressing environmental concerns.</div></div>","PeriodicalId":345,"journal":{"name":"Journal of Analytical and Applied Pyrolysis","volume":"192 ","pages":"Article 107308"},"PeriodicalIF":6.2000,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"End-of-life wind turbine blades as a resource: A comparative study of pyrolysis and combustion\",\"authors\":\"Sibel Başakçılardan Kabakcı , Ayşe Şenlik\",\"doi\":\"10.1016/j.jaap.2025.107308\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The transition to a low-carbon economy has accelerated wind energy installations. However, managing waste wind turbine blades (WTBs) remains a challenge due to their composite nature and limited regulations. This study explores the thermochemical recovery of WTBs via pyrolysis and combustion, focusing on gaseous emissions, pyrolysis oil, pyrochar morphology and ash. WTBs exhibit low carbon content (29.5 wt%), a heating value of 12 MJ/kg, and high ash content (58 wt%), meeting the minimum fuel threshold for cement production but not EN 15359 standards. Pyrolysis tests revealed decomposition behavior (T<sub>onset</sub>: 348 °C, T<sub>peak</sub>: 390 °C, T<sub>offset</sub>:421 °C) with a 39.3 % conversion rate. TG-FTIR analysis identified alcohols, esters, phenolics, and carbonyl groups, with key volatiles released at 366–417 °C. Pyrolysis oil (C6-C40, dominated by C15) was rich in Bisphenol A derivatives, suitable for resin production. Pyrochar, primarily glass fiber, exhibited low carbon content, making it suitable as a concrete or polymer additive. Combustion tests showed a mean ignition temperature of 276 °C, burnout at 686.5 °C, and moderate combustibility index. CO<sub>2</sub> emissions peaked between 421 and 572 °C. Ash morphology revealed glass fibers surrounded by loosely adherent ash. These findings support WTB valorization, promoting energy and material recovery while addressing environmental concerns.</div></div>\",\"PeriodicalId\":345,\"journal\":{\"name\":\"Journal of Analytical and Applied Pyrolysis\",\"volume\":\"192 \",\"pages\":\"Article 107308\"},\"PeriodicalIF\":6.2000,\"publicationDate\":\"2025-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Analytical and Applied Pyrolysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0165237025003614\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical and Applied Pyrolysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0165237025003614","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
End-of-life wind turbine blades as a resource: A comparative study of pyrolysis and combustion
The transition to a low-carbon economy has accelerated wind energy installations. However, managing waste wind turbine blades (WTBs) remains a challenge due to their composite nature and limited regulations. This study explores the thermochemical recovery of WTBs via pyrolysis and combustion, focusing on gaseous emissions, pyrolysis oil, pyrochar morphology and ash. WTBs exhibit low carbon content (29.5 wt%), a heating value of 12 MJ/kg, and high ash content (58 wt%), meeting the minimum fuel threshold for cement production but not EN 15359 standards. Pyrolysis tests revealed decomposition behavior (Tonset: 348 °C, Tpeak: 390 °C, Toffset:421 °C) with a 39.3 % conversion rate. TG-FTIR analysis identified alcohols, esters, phenolics, and carbonyl groups, with key volatiles released at 366–417 °C. Pyrolysis oil (C6-C40, dominated by C15) was rich in Bisphenol A derivatives, suitable for resin production. Pyrochar, primarily glass fiber, exhibited low carbon content, making it suitable as a concrete or polymer additive. Combustion tests showed a mean ignition temperature of 276 °C, burnout at 686.5 °C, and moderate combustibility index. CO2 emissions peaked between 421 and 572 °C. Ash morphology revealed glass fibers surrounded by loosely adherent ash. These findings support WTB valorization, promoting energy and material recovery while addressing environmental concerns.
期刊介绍:
The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.