基于环己基配体的二维/三维钙钛矿太阳能电池界面钝化增强的空间原子排列（Small 30/2025）

IF 12.1 2区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Small Pub Date : 2025-07-29 DOI:10.1002/smll.202570229

Yonghoon Jung, Seong Ho Cho, Seongheon Kim, Jieun Lee, Ki Tae Park, Yun Seog Lee

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引用次数: 0

摘要

钙钛矿太阳能电池钙钛矿太阳能电池中顺式和反式羟基化环己基铵配体的比较研究揭示了与[PbI6]4−八面体的不同界面相互作用。顺式异构体优先锚定在3D钙钛矿表面，形成2D/3D异质结，实现有效的缺陷钝化，并促进钙钛矿- html界面上有效的空穴提取，从而增强电荷传输和器件性能。详见文章编号2501564，Yun Seog Lee及其同事。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Spatial Atomic Arrangement of Cyclohexyl-Based Ligands for Enhanced Interface Passivation in 2D/3D Perovskite Solar Cells (Small 30/2025)

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Spatial Atomic Arrangement of Cyclohexyl-Based Ligands for Enhanced Interface Passivation in 2D/3D Perovskite Solar Cells (Small 30/2025)

Perovskite Solar Cells

A comparative study of cis- and trans-hydroxylated cyclohexylammonium ligands in perovskite solar cells reveals distinct interfacial interactions with [PbI₆]⁴⁻ octahedra. The cis isomer preferentially anchors onto the 3D perovskite surface, forming a 2D/3D heterojunction that enables effective defect passivation and promotes efficient hole extraction across the perovskite–HTL interface, thereby enhancing charge transport and device performance. More in article number 2501564, Yun Seog Lee and co-workers.

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来源期刊

Small 工程技术-材料科学：综合

CiteScore

17.70

自引率

3.80%

发文量

1830

审稿时长

2.1 months

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