非晶态碱式碳酸钴转移加氢的酸碱位协同作用和晶格畸变

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-28 DOI:10.1039/D5CC03182F

Mengxin Wang, Chenyang Lu, Shihong Zhou, Yao Fan, Qun Li, Cailong Zhou, Luxi Tan and Lichun Dong

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引用次数: 0

摘要

通过易沉淀法合成的无定形碱式碳酸钴在肉桂醛转移加氢反应中表现出比氧化钴催化剂更高的活性（转化率为97.1%，选择性为98.0%），这主要得益于其高密度的酸碱位和晶格畸变。本工作为转移加氢反应提供了一种有效的催化剂设计。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synergizing acid–base sites and lattice distortion of amorphous basic cobalt carbonate for transfer hydrogenation

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Synergizing acid–base sites and lattice distortion of amorphous basic cobalt carbonate for transfer hydrogenation

The amorphous basic cobalt carbonate synthesized via a facile precipitation method exhibits much higher activity (97.1% conversion and 98.0% selectivity) in cinnamaldehyde transfer hydrogenation compared to cobalt oxide catalysts, due to the high-density acid–base sites and lattice distortion. This work offers an effective catalyst design for transfer hydrogenation reactions.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.