Xingyue Wang , Jia Wang , Haoxuan Ding , Minghu Pan
{"title":"二维有机拓扑绝缘体的研究进展:表面合成与表征","authors":"Xingyue Wang , Jia Wang , Haoxuan Ding , Minghu Pan","doi":"10.1016/j.surfrep.2025.100660","DOIUrl":null,"url":null,"abstract":"<div><div>Two-dimensional (2D) organic topological insulators (OTIs) have garnered increasing interest due to their SOC-induced band gaps and topological boundary states that connect the valence and conduction bands. Experimental efforts utilizing substrate-mediated self-assembly have successfully fabricated 2D organic frameworks with various lattice symmetries. The vast diversity of organic molecules and the wide range of possible coordination interactions between organic ligands and metal atoms have led to significant attention toward these frameworks. However, the experimental realization of large-scale, ordered 2D OTIs remains challenging. In particular, the synthesis of monolayer 2D OTIs featuring nearly flat bands due to destructive quantum interference near the Fermi level has been elusive. With advancements in synthetic chemistry and on-surface synthesis techniques, the number of theoretically-predicted 2D OTIs has been gradually experimentally realized. This review provides a comprehensive summary of recent advances in the synthesis and characterization of 2D OTIs, with a particular focus on the experimental identification of nontrivial flat bands. Finally, we discuss future research directions and the challenges associated with characterizing these novel quantum materials.</div></div>","PeriodicalId":434,"journal":{"name":"Surface Science Reports","volume":"80 2","pages":"Article 100660"},"PeriodicalIF":8.7000,"publicationDate":"2025-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances of two-dimensional organic topological insulators: surface synthesis and characterization\",\"authors\":\"Xingyue Wang , Jia Wang , Haoxuan Ding , Minghu Pan\",\"doi\":\"10.1016/j.surfrep.2025.100660\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Two-dimensional (2D) organic topological insulators (OTIs) have garnered increasing interest due to their SOC-induced band gaps and topological boundary states that connect the valence and conduction bands. Experimental efforts utilizing substrate-mediated self-assembly have successfully fabricated 2D organic frameworks with various lattice symmetries. The vast diversity of organic molecules and the wide range of possible coordination interactions between organic ligands and metal atoms have led to significant attention toward these frameworks. However, the experimental realization of large-scale, ordered 2D OTIs remains challenging. In particular, the synthesis of monolayer 2D OTIs featuring nearly flat bands due to destructive quantum interference near the Fermi level has been elusive. With advancements in synthetic chemistry and on-surface synthesis techniques, the number of theoretically-predicted 2D OTIs has been gradually experimentally realized. This review provides a comprehensive summary of recent advances in the synthesis and characterization of 2D OTIs, with a particular focus on the experimental identification of nontrivial flat bands. Finally, we discuss future research directions and the challenges associated with characterizing these novel quantum materials.</div></div>\",\"PeriodicalId\":434,\"journal\":{\"name\":\"Surface Science Reports\",\"volume\":\"80 2\",\"pages\":\"Article 100660\"},\"PeriodicalIF\":8.7000,\"publicationDate\":\"2025-07-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Science Reports\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167572925000081\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Science Reports","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167572925000081","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Recent advances of two-dimensional organic topological insulators: surface synthesis and characterization
Two-dimensional (2D) organic topological insulators (OTIs) have garnered increasing interest due to their SOC-induced band gaps and topological boundary states that connect the valence and conduction bands. Experimental efforts utilizing substrate-mediated self-assembly have successfully fabricated 2D organic frameworks with various lattice symmetries. The vast diversity of organic molecules and the wide range of possible coordination interactions between organic ligands and metal atoms have led to significant attention toward these frameworks. However, the experimental realization of large-scale, ordered 2D OTIs remains challenging. In particular, the synthesis of monolayer 2D OTIs featuring nearly flat bands due to destructive quantum interference near the Fermi level has been elusive. With advancements in synthetic chemistry and on-surface synthesis techniques, the number of theoretically-predicted 2D OTIs has been gradually experimentally realized. This review provides a comprehensive summary of recent advances in the synthesis and characterization of 2D OTIs, with a particular focus on the experimental identification of nontrivial flat bands. Finally, we discuss future research directions and the challenges associated with characterizing these novel quantum materials.
期刊介绍:
Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.