二次生长金属有机骨架的制备及其应用前景

IF 4.7 3区材料科学 Q1 CHEMISTRY, APPLIED

Microporous and Mesoporous Materials Pub Date : 2025-07-25 DOI:10.1016/j.micromeso.2025.113782

Yongbo Hou , Zhaotian Wang , Lu Zhang , Xin Liu , Xufeng Dong

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引用次数: 0

摘要

金属有机框架（mof）从最初的发现到在各个领域的广泛应用，经历了快速的发展。它们多样的结构形式和广泛的功能范围使它们具有高度的通用性。以膜形式合成的MOFs能够实现高效的气体分离和吸附，有助于环境净化和水资源管理。这些应用的关键在于能够制造致密、无缺陷的膜结构，而二次生长被证明是一种有效的策略。介绍了二次生长过程中晶体种类、载体、接种方式和生长方式的影响因素，并对其应用进行了总结。为高质量mof膜的合成提供了指导和选择。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Preparation of secondary growth of metal organic frameworks and potential applications

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Preparation of secondary growth of metal organic frameworks and potential applications

Metal-organic frameworks (MOFs) have undergone rapid development, evolving from their initial discovery to widespread applications across various fields. Their diverse structural forms and extensive ranges of functionalities make them highly versatile. Synthesizing MOFs in membrane form enables efficient gas separation and adsorption, contributing to environmental purification and water resource management. The key to these applications lies in the ability to fabricate dense, defect-free membrane structures, for which secondary growth proves to be an effective strategy. By introducing the influencing factors of crystal species, support, inoculation method and growth method in the secondary growth process, together with the summarization of the applications. Guidance and options can be provided for synthesizing high-quality MOFs membranes.

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来源期刊

Microporous and Mesoporous Materials 化学-材料科学：综合

CiteScore

10.70

自引率

5.80%

发文量

649

审稿时长

26 days

期刊介绍： Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal. Topics which are particularly of interest include: All aspects of natural microporous and mesoporous solids The synthesis of crystalline or amorphous porous materials The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials Adsorption (and other separation techniques) using microporous or mesoporous adsorbents Catalysis by microporous and mesoporous materials Host/guest interactions Theoretical chemistry and modelling of host/guest interactions All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.