{"title":"探究胺-水混合物的极性结构-功能关系","authors":"Elizabeth Dach, Elone Pisacane, Devon Campbell, Lindsay Soh, Ngai Yin Yip","doi":"10.1039/d5cc03314d","DOIUrl":null,"url":null,"abstract":"This study investigates the relationships between chemical structure, polarity, and miscibility in solvent-water systems to elucidate the mechanisms underlying the thermoresponsive hydrophilicity of amines. By integrating complementary analyses of Kamlet-Taft parameters and relative permittivity, we elucidate that hydrogen bonding and nanoscale ordering, i.e., molecular-level and mean-field, respectively, underlie amine-water interactions, which, in turn, influence the thermomorphic hydrophilicity function.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"707 1","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Probing Polarity Structure-Function Relationships in Amine-Water Mixtures\",\"authors\":\"Elizabeth Dach, Elone Pisacane, Devon Campbell, Lindsay Soh, Ngai Yin Yip\",\"doi\":\"10.1039/d5cc03314d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study investigates the relationships between chemical structure, polarity, and miscibility in solvent-water systems to elucidate the mechanisms underlying the thermoresponsive hydrophilicity of amines. By integrating complementary analyses of Kamlet-Taft parameters and relative permittivity, we elucidate that hydrogen bonding and nanoscale ordering, i.e., molecular-level and mean-field, respectively, underlie amine-water interactions, which, in turn, influence the thermomorphic hydrophilicity function.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"707 1\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc03314d\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc03314d","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Probing Polarity Structure-Function Relationships in Amine-Water Mixtures
This study investigates the relationships between chemical structure, polarity, and miscibility in solvent-water systems to elucidate the mechanisms underlying the thermoresponsive hydrophilicity of amines. By integrating complementary analyses of Kamlet-Taft parameters and relative permittivity, we elucidate that hydrogen bonding and nanoscale ordering, i.e., molecular-level and mean-field, respectively, underlie amine-water interactions, which, in turn, influence the thermomorphic hydrophilicity function.
期刊介绍:
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