从镧到锎的低价f元素分子络合物

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews Pub Date : 2025-07-25 DOI:10.1016/j.ccr.2025.217004

Hannah B. Wineinger, Joseph M. Sperling, Thomas E. Albrecht

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引用次数: 0

摘要

本文综述了二价镧系元素和锕系元素在小分子体系中的结构和化学性质，重点介绍了不易接近的二价镧系元素，如结构交叉（Dy2+, Nd2+）和非传统镧系元素（II）（La2+, Ce2+, Pr2+, Gd2+, Tb2+, Ho2+， Er2+和Lu2+）和不易接近的锕系元素（II）。广泛的进展，包括最近的低氧化态f块化学合成的第一次，回顾和分析，为未来的合成工作建立知识。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Molecular complexes of low-valent f-elements from lanthanum to californium

This review outlines the structure and chemistry of divalent lanthanides and actinides in small molecule systems, focusing on the less accessible divalent lanthanides such as the configurational crossover (Dy²⁺, Nd²⁺) and non-traditional lanthanides(II) (La²⁺, Ce²⁺, Pr²⁺, Gd²⁺, Tb²⁺, Ho²⁺, Er²⁺, and Lu²⁺) and the rarely accessible actinides(II). Expansive progress, including recent synthetic firsts in low-oxidation state f-block chemistry, are reviewed and analyzed to build knowledge for future synthetic efforts.

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来源期刊

Coordination Chemistry Reviews 化学-无机化学与核化学

CiteScore

34.30

自引率

5.30%

发文量

457

审稿时长

54 days

期刊介绍： Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.