纳米颗粒包封的有机磁凝胶:交联网络用于广谱污染物去除

IF 11.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL
Sanjeevi Prasath Sridhar, Sudha Uthaman, Logesh Kumar Pandurangan, Armin Kriele, Debasish Saha, Baohu Wu, Velraj Parthiban, Janaki Vembu Murugesan, Balachandar Vijayakumar, Stephan Förster, Aurel Radulescu, Brijitta Joseph
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引用次数: 0

摘要

在这篇论文中,我们报道了一种用于高性能污染物吸附的聚(4-乙烯基吡啶)-还原氧化石墨烯-磁铁矿(P4VP-rGO-Fe₃O₄)有机磁性聚合物(OMG)的合成。在OMG中,rGO和Fe₃O₄纳米颗粒在4-乙烯基吡啶聚合物的化学交联过程中被原位封装。采用有机染料、重金属离子和水媒病原体三种模型水污染物对OMG的吸附性能进行了评价。对有机染料的平衡吸附量超过400 mg/g。除染料外,OMG还能吸附重金属离子,如AsO2−、Pb 2 +、Cr2O72−和Cd 2 +,去除效率超过60%,吸附量超过200 mg/g。OMG对大肠杆菌和伤寒沙门氏菌也表现出显著的抑菌活性,对伤寒沙门氏菌的抑菌活性几乎为零。OMG承诺在废水处理中具有广泛的适用性,为水净化提供了可持续和高效的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Nanoparticle-encapsulated organo-magnetogels: crosslinked network for broad-spectrum pollutant removal

Nanoparticle-encapsulated organo-magnetogels: crosslinked network for broad-spectrum pollutant removal

In this contribution, we report the synthesis of a poly(4-vinylpyridine)-reduced graphene oxide-magnetite (P4VP-rGO-Fe₃O₄) organo-magnetogel (OMG), designed for high-performance pollutant adsorption. In the OMG, rGO and Fe₃O₄ nanoparticles are in situ encapsulated during the chemical cross-linking of the 4-vinylpyridine polymer. The adsorption performance of OMG was evaluated using three model water pollutants, viz., organic dyes, heavy metal ions, and waterborne pathogens. The equilibrium adsorption capacity exceeded 400 mg/g for the organic dyes. Beyond dye removal, the OMG also adsorbed heavy metal ions, such as AsO2, Pb²⁺, Cr2O72−, and Cd²⁺ ions, with removal efficiencies exceeding 60% and adsorption capacities exceeding 200 mg/g. The OMG also exhibited remarkable antibacterial activity against E. coli and S. Typhi, with almost zero viability for S. Typhi. The OMG promises a broad-spectrum applicability in wastewater treatment, offering a sustainable and efficient solution for water decontamination.

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来源期刊
npj Clean Water
npj Clean Water Environmental Science-Water Science and Technology
CiteScore
15.30
自引率
2.60%
发文量
61
审稿时长
5 weeks
期刊介绍: npj Clean Water publishes high-quality papers that report cutting-edge science, technology, applications, policies, and societal issues contributing to a more sustainable supply of clean water. The journal's publications may also support and accelerate the achievement of Sustainable Development Goal 6, which focuses on clean water and sanitation.
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