Piotr Rytlewski , Piotr Augustyn , Rafał Malinowski , Bogusław Budner , Arkadiusz Antończak
{"title":"利用新型电镀技术对丙烯腈-丁二烯-苯乙烯(ABS)复合材料进行表面金属化","authors":"Piotr Rytlewski , Piotr Augustyn , Rafał Malinowski , Bogusław Budner , Arkadiusz Antończak","doi":"10.1016/j.apsusc.2025.164146","DOIUrl":null,"url":null,"abstract":"<div><div>This study presents a novel approach to the direct metallisation of polymer composites. The investigated composites were based on an acrylonitrile–butadiene–styrene (ABS) matrix and incorporated conductive fillers consisting of various ratio of copper fibres to tin powder, with a total filler content of 25 vol%. Ultraviolet (UV) laser irradiation (λ = 343 nm) selectively ablated the polymer matrix and exposed the embedded conductive fillers. Subsequent infrared (IR) laser irradiation (λ = 1030 nm) partially melted the tin and promoted its bonding with the copper fibres. This sequence produced an electrically conductive surface layer. The modified surfaces were subsequently subjected to electroplating, which effectively resulted in copper coatings. Changes in surface geometry and chemical structure arising from the sequential laser treatment (UV followed by IR) were characterised. In addition, the adhesion strength of the deposited metallic coatings was evaluated.</div></div>","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"712 ","pages":"Article 164146"},"PeriodicalIF":6.9000,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Surface metallisation of acrylonitrile–butadiene–styrene (ABS) composites via a novel electroplating technique\",\"authors\":\"Piotr Rytlewski , Piotr Augustyn , Rafał Malinowski , Bogusław Budner , Arkadiusz Antończak\",\"doi\":\"10.1016/j.apsusc.2025.164146\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study presents a novel approach to the direct metallisation of polymer composites. The investigated composites were based on an acrylonitrile–butadiene–styrene (ABS) matrix and incorporated conductive fillers consisting of various ratio of copper fibres to tin powder, with a total filler content of 25 vol%. Ultraviolet (UV) laser irradiation (λ = 343 nm) selectively ablated the polymer matrix and exposed the embedded conductive fillers. Subsequent infrared (IR) laser irradiation (λ = 1030 nm) partially melted the tin and promoted its bonding with the copper fibres. This sequence produced an electrically conductive surface layer. The modified surfaces were subsequently subjected to electroplating, which effectively resulted in copper coatings. Changes in surface geometry and chemical structure arising from the sequential laser treatment (UV followed by IR) were characterised. In addition, the adhesion strength of the deposited metallic coatings was evaluated.</div></div>\",\"PeriodicalId\":247,\"journal\":{\"name\":\"Applied Surface Science\",\"volume\":\"712 \",\"pages\":\"Article 164146\"},\"PeriodicalIF\":6.9000,\"publicationDate\":\"2025-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Surface Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169433225018616\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Surface Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169433225018616","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Surface metallisation of acrylonitrile–butadiene–styrene (ABS) composites via a novel electroplating technique
This study presents a novel approach to the direct metallisation of polymer composites. The investigated composites were based on an acrylonitrile–butadiene–styrene (ABS) matrix and incorporated conductive fillers consisting of various ratio of copper fibres to tin powder, with a total filler content of 25 vol%. Ultraviolet (UV) laser irradiation (λ = 343 nm) selectively ablated the polymer matrix and exposed the embedded conductive fillers. Subsequent infrared (IR) laser irradiation (λ = 1030 nm) partially melted the tin and promoted its bonding with the copper fibres. This sequence produced an electrically conductive surface layer. The modified surfaces were subsequently subjected to electroplating, which effectively resulted in copper coatings. Changes in surface geometry and chemical structure arising from the sequential laser treatment (UV followed by IR) were characterised. In addition, the adhesion strength of the deposited metallic coatings was evaluated.
期刊介绍:
Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.