不对称连接产生具有局部MOF-74结构的内在无序金属有机骨架。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-11 DOI:10.1039/d5cc03713a

Bhavish Dinakar , Julius J. Oppenheim , Marco Vandone , Juan F. Torres , Andrei Iliescu , Zhentao Yang , Yuriy Román-Leshkov , Mircea Dincă

引用次数: 0

摘要

在这里，我们报道了MOF-74家族中的一个内在无序的MOF， Mg2-x(as-dobpdc) （as-dobpdc4- = 3‘，4-二氧化联苯-3,4’-二羧酸盐）。尽管缺乏结晶度，这种材料表现出与其晶体异构体一致的局部有序，保持孔隙度，并表现出高密度的开放金属位点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure†

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Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure†

Here, we report an intrinsically disordered MOF in the MOF-74 family, Mg_2−x(as-dobpdc) (as-dobpdc⁴⁻ = 3′,4-dioxidobiphenyl-3,4′-dicarboxylate). Despite the absence of crystallinity, this material exhibits local ordering consistent with that of its crystalline isomers, maintains porosity, and exhibits a high density of open metal sites.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.