Gao Tongyu, Zan Yongxi, Qian Zhao, Wang Chenger, Duan Mobin, , Chen Xiaoxia, Liu Yuanhong, Liu Ronghui
{"title":"稀土发光材料的发展现状","authors":"Gao Tongyu, Zan Yongxi, Qian Zhao, Wang Chenger, Duan Mobin, , Chen Xiaoxia, Liu Yuanhong, Liu Ronghui","doi":"10.1016/j.jallcom.2025.182399","DOIUrl":null,"url":null,"abstract":"Rare earth luminescence materials which have garnered significant attention and advanced rapidly in fields such as general lighting, backlight display applications, information detection, photoelectric devices, modern agriculture, optical storage, and anti-counterfeiting, represent a crucial research direction within rare earth materials science. Rare earth luminescence materials encompass a diverse range, categorized into several key types: (1) High-performance phosphors, including Eu<sup>2+</sup>/Ce<sup>3+</sup>-activated nitrides and oxynitrides for full-spectrum applications—such as Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>: Ce<sup>3+</sup> and Sr<sub>2</sub>Si<sub>5</sub>N<sub>8</sub>: Eu<sup>2+</sup> for lighting, and wide-gamut liquid crystal display (LCD) backlights, exemplified by β-SiAlON: Eu<sup>2+</sup> green phosphors and K<sub>2</sub>SiF<sub>6</sub>: Mn<sup>4+</sup> red phosphors; (2) Cr<sup>3+</sup>-doped garnets and gallates, which serve as leading near-infrared (NIR) phosphors for phosphor-converted LEDs (pc-LEDs), emitting in the 750–1100<!-- --> <!-- -->nm range with a full width at half maximum (FWHM) <100<!-- --> <!-- -->nm; (3) Er<sup>3+</sup>/Yb<sup>3+</sup> up-conversion systems for optical sensing; (4) Eu<sup>3+</sup>/Tb<sup>3+</sup> bulk luminescence materials for radiation detection; and (5) Ln<sup>3+</sup>-doped (Ln = Dy, Eu) persistent phosphors and lanthanide-complex anti-counterfeiting inks. This article highlights advancements in mechanistic investigations, as well as the current status of technical and industrial development in rare earth luminescence materials. Special focus is placed on analyzing key categories: full-spectrum lighting phosphors, wide color gamut LCD backlight phosphors, pc-LED phosphors for NIR emission, up-conversion luminescence materials, bulk luminescence materials, temperature-sensitive detection luminescence materials, Persistent luminescence (PersL) materials, anti-counterfeiting materials, and the industrial development of rare earth luminescence materials. Additionally, potential challenges and future trends in this field are discussed. Future development pathways will center on defect engineering, the discovery of novel host matrices, and sustainable manufacturing to overcome existing barriers.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"18 1","pages":""},"PeriodicalIF":6.3000,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development Status of Rare Earth Luminescence Material\",\"authors\":\"Gao Tongyu, Zan Yongxi, Qian Zhao, Wang Chenger, Duan Mobin, , Chen Xiaoxia, Liu Yuanhong, Liu Ronghui\",\"doi\":\"10.1016/j.jallcom.2025.182399\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rare earth luminescence materials which have garnered significant attention and advanced rapidly in fields such as general lighting, backlight display applications, information detection, photoelectric devices, modern agriculture, optical storage, and anti-counterfeiting, represent a crucial research direction within rare earth materials science. Rare earth luminescence materials encompass a diverse range, categorized into several key types: (1) High-performance phosphors, including Eu<sup>2+</sup>/Ce<sup>3+</sup>-activated nitrides and oxynitrides for full-spectrum applications—such as Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>: Ce<sup>3+</sup> and Sr<sub>2</sub>Si<sub>5</sub>N<sub>8</sub>: Eu<sup>2+</sup> for lighting, and wide-gamut liquid crystal display (LCD) backlights, exemplified by β-SiAlON: Eu<sup>2+</sup> green phosphors and K<sub>2</sub>SiF<sub>6</sub>: Mn<sup>4+</sup> red phosphors; (2) Cr<sup>3+</sup>-doped garnets and gallates, which serve as leading near-infrared (NIR) phosphors for phosphor-converted LEDs (pc-LEDs), emitting in the 750–1100<!-- --> <!-- -->nm range with a full width at half maximum (FWHM) <100<!-- --> <!-- -->nm; (3) Er<sup>3+</sup>/Yb<sup>3+</sup> up-conversion systems for optical sensing; (4) Eu<sup>3+</sup>/Tb<sup>3+</sup> bulk luminescence materials for radiation detection; and (5) Ln<sup>3+</sup>-doped (Ln = Dy, Eu) persistent phosphors and lanthanide-complex anti-counterfeiting inks. This article highlights advancements in mechanistic investigations, as well as the current status of technical and industrial development in rare earth luminescence materials. Special focus is placed on analyzing key categories: full-spectrum lighting phosphors, wide color gamut LCD backlight phosphors, pc-LED phosphors for NIR emission, up-conversion luminescence materials, bulk luminescence materials, temperature-sensitive detection luminescence materials, Persistent luminescence (PersL) materials, anti-counterfeiting materials, and the industrial development of rare earth luminescence materials. Additionally, potential challenges and future trends in this field are discussed. Future development pathways will center on defect engineering, the discovery of novel host matrices, and sustainable manufacturing to overcome existing barriers.\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jallcom.2025.182399\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jallcom.2025.182399","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Development Status of Rare Earth Luminescence Material
Rare earth luminescence materials which have garnered significant attention and advanced rapidly in fields such as general lighting, backlight display applications, information detection, photoelectric devices, modern agriculture, optical storage, and anti-counterfeiting, represent a crucial research direction within rare earth materials science. Rare earth luminescence materials encompass a diverse range, categorized into several key types: (1) High-performance phosphors, including Eu2+/Ce3+-activated nitrides and oxynitrides for full-spectrum applications—such as Y3Al5O12: Ce3+ and Sr2Si5N8: Eu2+ for lighting, and wide-gamut liquid crystal display (LCD) backlights, exemplified by β-SiAlON: Eu2+ green phosphors and K2SiF6: Mn4+ red phosphors; (2) Cr3+-doped garnets and gallates, which serve as leading near-infrared (NIR) phosphors for phosphor-converted LEDs (pc-LEDs), emitting in the 750–1100 nm range with a full width at half maximum (FWHM) <100 nm; (3) Er3+/Yb3+ up-conversion systems for optical sensing; (4) Eu3+/Tb3+ bulk luminescence materials for radiation detection; and (5) Ln3+-doped (Ln = Dy, Eu) persistent phosphors and lanthanide-complex anti-counterfeiting inks. This article highlights advancements in mechanistic investigations, as well as the current status of technical and industrial development in rare earth luminescence materials. Special focus is placed on analyzing key categories: full-spectrum lighting phosphors, wide color gamut LCD backlight phosphors, pc-LED phosphors for NIR emission, up-conversion luminescence materials, bulk luminescence materials, temperature-sensitive detection luminescence materials, Persistent luminescence (PersL) materials, anti-counterfeiting materials, and the industrial development of rare earth luminescence materials. Additionally, potential challenges and future trends in this field are discussed. Future development pathways will center on defect engineering, the discovery of novel host matrices, and sustainable manufacturing to overcome existing barriers.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.