{"title":"控制纳米材料组装的非共价相互作用的分子工程:化学原理和材料设计","authors":"Navid Rabiee , Mohammad Rabiee","doi":"10.1016/j.ccr.2025.217005","DOIUrl":null,"url":null,"abstract":"<div><div>Non-covalent interactions (NCIs) are pivotal in directing nanomaterial assembly, offering tunability and reversibility absent in traditional covalent methods. This review explores the foundational thermodynamic and kinetic principles underlying NCI-driven processes, the quantum and classical mechanical modeling used for design, characterization techniques used in evaluating nanomaterials, and the primary classes of NCIs. Key topics include coordination, π-π stacking, hydrogen bonding, and host-guest chemistry, and their interplay in controlling assembly. Emerging approaches that combine disparate NCIs or connect molecular systems to advanced computational techniques that use large datasets are also highlighted. This work examines challenges, opportunities, emerging techniques, and the use of the most sophisticated modeling to showcase the promise of these powerful methods in the ever-expanding field of soft nanomaterials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"545 ","pages":"Article 217005"},"PeriodicalIF":23.5000,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Molecular engineering of non-covalent interactions for controlled nanomaterial assembly: Chemical principles and materials design\",\"authors\":\"Navid Rabiee , Mohammad Rabiee\",\"doi\":\"10.1016/j.ccr.2025.217005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Non-covalent interactions (NCIs) are pivotal in directing nanomaterial assembly, offering tunability and reversibility absent in traditional covalent methods. This review explores the foundational thermodynamic and kinetic principles underlying NCI-driven processes, the quantum and classical mechanical modeling used for design, characterization techniques used in evaluating nanomaterials, and the primary classes of NCIs. Key topics include coordination, π-π stacking, hydrogen bonding, and host-guest chemistry, and their interplay in controlling assembly. Emerging approaches that combine disparate NCIs or connect molecular systems to advanced computational techniques that use large datasets are also highlighted. This work examines challenges, opportunities, emerging techniques, and the use of the most sophisticated modeling to showcase the promise of these powerful methods in the ever-expanding field of soft nanomaterials.</div></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":\"545 \",\"pages\":\"Article 217005\"},\"PeriodicalIF\":23.5000,\"publicationDate\":\"2025-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854525005752\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854525005752","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Molecular engineering of non-covalent interactions for controlled nanomaterial assembly: Chemical principles and materials design
Non-covalent interactions (NCIs) are pivotal in directing nanomaterial assembly, offering tunability and reversibility absent in traditional covalent methods. This review explores the foundational thermodynamic and kinetic principles underlying NCI-driven processes, the quantum and classical mechanical modeling used for design, characterization techniques used in evaluating nanomaterials, and the primary classes of NCIs. Key topics include coordination, π-π stacking, hydrogen bonding, and host-guest chemistry, and their interplay in controlling assembly. Emerging approaches that combine disparate NCIs or connect molecular systems to advanced computational techniques that use large datasets are also highlighted. This work examines challenges, opportunities, emerging techniques, and the use of the most sophisticated modeling to showcase the promise of these powerful methods in the ever-expanding field of soft nanomaterials.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.