四氟吡啶调控铂/钯在1,4-不对称C60核上的位点选择性配位一锅纯异构体合成1,4-二有机[60]富勒烯配合物

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-07-24 DOI:10.1021/acs.inorgchem.5c01723

Jin-Ying Liu,Yi-Long Li,Zheng-Chun Yin,Jun Xuan,Hong-Ping Zhou,Fei Li

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引用次数: 0

摘要

1-有机-4-（4′-四氟吡啶基）[60]富勒烯是一种高效的有机富勒烯配体，可与铂和钯进行选择性的η - 2配位。实验结果和理论计算表明，C60的1,4-不对称修饰结构中的四氟吡啶基团在调控位点选择性中起着至关重要的作用。此外，还成功地实现了C60与吲哚、五氟吡啶和M(PPh3)4 （M = Pt, Pd）的一锅高位点选择性三功能化。

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One-Pot Isomer-Pure Synthesis of 1,4-Diorgano[60]fullerene Complexes via Tetrafluoropyridine Regulated Site-Selective Coordination of Platinum/Palladium on the 1,4-Unsymmetric C60 Core.

1-Organo-4-(4'-tetrafluoropyridyl)[60]fullerenes have been developed as an efficient organic fullerene ligand for site-selective η2-coordination with platinum and palladium. Experimental results and theoretical calculations indicate that the tetrafluoropyridine groups in the 1,4-asymmetrically modified structure of C60 play a crucial role in regulating site selectivity. Furthermore, a one-pot, highly site-selective trifunctionalization of C60 with indole, pentafluoropyridine, and M(PPh3)4 (M = Pt, Pd) has been successfully achieved.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.