封面图：z -乙烯基硫化物的区域、立体选择性、有氧和无金属合成：内炔的一锅加氢碘化和原位磺化（ad . Synth）。Catal。13/2025)

IF 4 2区化学 Q2 CHEMISTRY, APPLIED

Advanced Synthesis & Catalysis Pub Date : 2025-07-24 DOI:10.1002/adsc.70032

Gloria Morís-Menéndez, Sergio E. García-Garrido, Pablo García-Álvarez, Alejandro Presa Soto, Nicolás Ríos-Lombardía, Joaquín García-Álvarez

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引用次数: 0

摘要

乙烯基硫化物艺术品中的两个相交平面代表了内部炔的加氢碘化和磺化的串联序列，合并在一个锅协议中。这种不含金属的转化在深度共晶溶剂（ChI/p-TsOH）中进行，可以在温和的有氧条件下高效地合成z -乙烯基硫化物，而不使用有毒的HI或VOCs。更多信息可以在Alejandro Presa Soto， Nicolás Ríos-Lombardía， Joaquín García-Álvarez和同事的文章编号2500388中找到。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Front Cover Picture: Regio-, Stereoselective, Aerobic and Metal-Free Synthesis of Z-Vinyl Sulfides: One-Pot Hydroiodination of Internal Alkynes and in situ Sulfenylations (Adv. Synth. Catal. 13/2025)

查看原文本刊更多论文

Front Cover Picture: Regio-, Stereoselective, Aerobic and Metal-Free Synthesis of Z-Vinyl Sulfides: One-Pot Hydroiodination of Internal Alkynes and in situ Sulfenylations (Adv. Synth. Catal. 13/2025)

Vinyl Sulfides

The two intersecting planes in the artwork represent the tandem sequence of hydroiodination and sulfenylation of internal alkynes, merged in a one-pot protocol. This metal-free transformation, conducted in a deep eutectic solvent (ChI/p-TsOH), enables the efficient and stereoselective synthesis of Z-vinyl sulfides under mild, aerobic conditions without using toxic HI or VOCs. More information can be found in article number 2500388 by Alejandro Presa Soto, Nicolás Ríos-Lombardía, Joaquín García-Álvarez, and co-workers.

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来源期刊

Advanced Synthesis & Catalysis 化学-应用化学

CiteScore

9.40

自引率

7.40%

发文量

447

审稿时长

1.8 months

期刊介绍： Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.