生物基bhmthf基聚合物的全景视图

IF 3.9 2区化学 Q2 POLYMER SCIENCE

Polymer Chemistry Pub Date : 2025-07-23 DOI:10.1039/d5py00544b

Cornelis Post, Dina Maniar, Rudy Folkersma, Vincent Voet, Katja Loos

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引用次数: 0

摘要

生物基化学平台5-羟甲基糠醛（HMF）被广泛认为是生产单体2,5-呋喃二羧酸（FDCA）和2,5-双羟基甲基呋喃（BHMF）的重要前体，后者用于生产可再生聚合物。与FDCA和BHMF一样，2,5-二（羟甲基）四氢呋喃（BHMTHF）可以由HMF合成，由于其双官能性，可以作为单体。BHMTHF，也被称为2,5-四氢呋喃二甲醇（THFDM），用于生产创新生物基聚合物的潜力仍未得到充分探索。这篇综述总结并强调了不同类型的聚酯和聚氨酯是从这种四氢呋喃构建块衍生的。BHMTHF由于其独特的杂环刚性、醚基的电负性和氢键能力，被预测为生产可持续聚合物的生物基单体具有光明的前景。这产生了各种聚合物，它们的结晶度降低或不存在，亲水性得到改善，剪切变薄行为明显。

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Panoramic View of Biobased BHMTHF-based Polymers

The biobased platform chemical 5-hydroxymethylfurfural (HMF) is widely recognized as an important precursor for the production of the monomer 2,5-furandicarboxylic acid (FDCA) and, to a lesser extent, 2,5-bishydroxymethyl furan (BHMF), which are used for the production of renewable polymers. Like FDCA and BHMF, 2,5-bis(hydroxymethyl)tetrahydrofuran (BHMTHF) can be synthesized from HMF and can act as a monomer due to its difunctionality. The potential of BHMTHF, also known as 2,5-tetrahydrofurandimethanol (THFDM), for use in the production of innovative biobased polymers is still underexplored. This review summarizes and highlights the different types of polyesters and polyurethanes that are derived from this tetrahydrofuran building block. BHMTHF is predicted to have a bright future as a biobased monomer for the production of sustainable polymers because of its unique heterocyclic rigidity, electronegativity of the ether group and hydrogen bonding ability. This yields various polymers with reduced or absent crystallinity, improved hydrophilicity and pronounced shear thinning behavior.

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来源期刊

Polymer Chemistry POLYMER SCIENCE-

CiteScore

8.60

自引率

8.70%

发文量

535

审稿时长

1.7 months

期刊介绍： Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.