Spin Me Right Round -一个多功能的基于bta的校准媒体工具箱，用于增强对映体辨别

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-08-04 DOI:10.1039/d5cc02116b

Matthias Brauser , Martin Leyendecker , Volker Schmidts , Christina M. Thiele

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引用次数: 0

摘要

苯三羧基酰胺（BTAs）是一种通过自组装形成溶致液晶（LLC）的模块。在这里，我们提出了一个基于bta的手性llc工具箱，作为测量残余偶极耦合（rdc）的对准介质。我们提出了一个基于新的不对称取代BTA的系统和一个基于手性和非手性BTA构建块混合物的中士和士兵（SaS）系统。研究了它们的对映性和可扩展性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Spin me right round – a versatile BTA-based alignment media toolbox for enhanced enantiodiscrimination†

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Spin me right round – a versatile BTA-based alignment media toolbox for enhanced enantiodiscrimination†

Benzenetricarboxamides (BTAs) have been introduced as modular building blocks forming lyotropic liquid crystals (LLC) by self-assembly. Herein, we present a toolbox of chiral BTA-based LLCs as alignment media for the measurement of residual dipolar couplings (RDCs). We present one system based on new asymmetrically substituted BTAs and a sergeant and soldier (SaS) system based on mixtures of chiral and achiral BTA building blocks. We investigate their enantiodiscriminating properties and scalability thereof.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.