二茂铁/苯基异噻唑-3-硫酮和异硒唑-3-硒酮新杂环的合成

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Deepak Sharma , Vijesh Tomar , Raj K. Joshi
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引用次数: 0

摘要

建立了二茂铁/苯基-β-氯丙醛、胺和硫粉(S和Se)环制新型杂环异噻唑-3-硫酮和异硒唑-3-硒酮的直接一锅法合成方法。该反应由环境友好的铁簇和Cu(OAc)2·H2O盐催化。这种方法是独特而罕见的,因为它由五个连续的键形成组成。其中1,2 N, S异硫唑-3-硫酮和异硒唑-3-硒酮化合物均为本文首次报道的新化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of ferrocenyl/phenyl isothiazole-3-thione and isoselenazole-3-selenone as new heterocycles

Synthesis of ferrocenyl/phenyl isothiazole-3-thione and isoselenazole-3-selenone as new heterocycles
A direct one-pot synthesis for novel heterocycles, isothiazole-3-thiones and isoselenazole-3-selenones via the annulation of ferrocenyl/phenyl-β-chloro acrylaldehyde, amines and chalcogen powder (S and Se) has been established. The reaction was catalyzed by an environmentally benign iron cluster and Cu(OAc)2·H2O salt. The method is unique and rare as it consists of five consecutive bonds formation. Herein, all the 1,2 N, S isothiozole-3-thione and isoselenazole-3-selenone compounds are new and reported for the first time in this paper.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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