{"title":"二茂铁/苯基异噻唑-3-硫酮和异硒唑-3-硒酮新杂环的合成","authors":"Deepak Sharma , Vijesh Tomar , Raj K. Joshi","doi":"10.1039/d5cc03270a","DOIUrl":null,"url":null,"abstract":"<div><div>A direct one-pot synthesis for novel heterocycles, isothiazole-3-thiones and isoselenazole-3-selenones <em>via</em> the annulation of ferrocenyl/phenyl-β-chloro acrylaldehyde, amines and chalcogen powder (S and Se) has been established. The reaction was catalyzed by an environmentally benign iron cluster and Cu(OAc)<sub>2</sub>·H<sub>2</sub>O salt. The method is unique and rare as it consists of five consecutive bonds formation. Herein, all the 1,2 N, S isothiozole-3-thione and isoselenazole-3-selenone compounds are new and reported for the first time in this paper.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 73","pages":"Pages 13964-13967"},"PeriodicalIF":4.2000,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of ferrocenyl/phenyl isothiazole-3-thione and isoselenazole-3-selenone as new heterocycles\",\"authors\":\"Deepak Sharma , Vijesh Tomar , Raj K. Joshi\",\"doi\":\"10.1039/d5cc03270a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A direct one-pot synthesis for novel heterocycles, isothiazole-3-thiones and isoselenazole-3-selenones <em>via</em> the annulation of ferrocenyl/phenyl-β-chloro acrylaldehyde, amines and chalcogen powder (S and Se) has been established. The reaction was catalyzed by an environmentally benign iron cluster and Cu(OAc)<sub>2</sub>·H<sub>2</sub>O salt. The method is unique and rare as it consists of five consecutive bonds formation. Herein, all the 1,2 N, S isothiozole-3-thione and isoselenazole-3-selenone compounds are new and reported for the first time in this paper.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 73\",\"pages\":\"Pages 13964-13967\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-08-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525017963\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525017963","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of ferrocenyl/phenyl isothiazole-3-thione and isoselenazole-3-selenone as new heterocycles
A direct one-pot synthesis for novel heterocycles, isothiazole-3-thiones and isoselenazole-3-selenones via the annulation of ferrocenyl/phenyl-β-chloro acrylaldehyde, amines and chalcogen powder (S and Se) has been established. The reaction was catalyzed by an environmentally benign iron cluster and Cu(OAc)2·H2O salt. The method is unique and rare as it consists of five consecutive bonds formation. Herein, all the 1,2 N, S isothiozole-3-thione and isoselenazole-3-selenone compounds are new and reported for the first time in this paper.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.