{"title":"前言:双齿卤素键供体的高对映选择性有机催化","authors":"","doi":"10.1002/anie.202583002","DOIUrl":null,"url":null,"abstract":"<p>Strike! A long-standing challenge was finally solved: achieving high enantioselectivity predominantly via halogen bonding (“XB”, see the red stitches) and on unbiased substrates. In their Communication (e202506476), Stefan M. Huber et al. describe the highly enantioselective catalysis of a Mukaiyama aldol reaction by bidentate halogen bond donors.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"64 30","pages":""},"PeriodicalIF":16.9000,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202583002","citationCount":"0","resultStr":"{\"title\":\"Frontispiece: Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors\",\"authors\":\"\",\"doi\":\"10.1002/anie.202583002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Strike! A long-standing challenge was finally solved: achieving high enantioselectivity predominantly via halogen bonding (“XB”, see the red stitches) and on unbiased substrates. In their Communication (e202506476), Stefan M. Huber et al. describe the highly enantioselective catalysis of a Mukaiyama aldol reaction by bidentate halogen bond donors.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":125,\"journal\":{\"name\":\"Angewandte Chemie International Edition\",\"volume\":\"64 30\",\"pages\":\"\"},\"PeriodicalIF\":16.9000,\"publicationDate\":\"2025-07-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202583002\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie International Edition\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/anie.202583002\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/anie.202583002","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
罢工!一个长期存在的挑战终于解决了:主要通过卤素键合(“XB”,见红色线)和无偏基片实现高对映体选择性。在他们的通讯(e202506476)中,Stefan M. Huber等人描述了双齿卤素键供体对Mukaiyama醛醇反应的高度对构选择性催化。
Frontispiece: Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors
Strike! A long-standing challenge was finally solved: achieving high enantioselectivity predominantly via halogen bonding (“XB”, see the red stitches) and on unbiased substrates. In their Communication (e202506476), Stefan M. Huber et al. describe the highly enantioselective catalysis of a Mukaiyama aldol reaction by bidentate halogen bond donors.
期刊介绍:
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.