Guijie Zhao , Hongzhan Guan , Huan Yan , Jinfeng Tian , Yafei Han , Jiaqi Wang , Yunkai Ruan , Liang Zhao , Feng Chen
{"title":"绿色创新:将盾构排放的废土和工业固体废物清洁转化为环保的高性能流动填料","authors":"Guijie Zhao , Hongzhan Guan , Huan Yan , Jinfeng Tian , Yafei Han , Jiaqi Wang , Yunkai Ruan , Liang Zhao , Feng Chen","doi":"10.1016/j.scp.2025.102125","DOIUrl":null,"url":null,"abstract":"<div><div>To address the high resource consumption and environmental burden of traditional fill materials, this study presents an environmentally friendly flowable fill using shield-discharged waste soil (SDWS), ground granulated blast-furnace slag (GGBFS), and fly ash as the main raw materials activated by a NaOH–Na<sub>2</sub>SiO<sub>3</sub> composite. Microstructural analysis, performance testing, and life cycle assessment (LCA) were conducted to systematically evaluate the reaction mechanisms, engineering properties, environmental impacts, and economic viability of the developed material. The results show that the prepared flowable fill has excellent workability and mechanical properties, with an initial flowability of 602–755 mm and a 28-day compressive strength of 6.43–8.98 MPa. The aggregate-to-binder ratio and alkali equivalent exert a more significant effect on the compressive strength than the liquid-to-solid ratio and activator modulus do. Microstructural analysis indicates that GGBFS and fly ash, under alkali activation, synergistically form dense C–S–H and C–A–S–H gels, improving the properties of the material. The LCA results reveal that the flowable fill achieves carbon dioxide equivalent (CO<sub>2</sub>-eq) emissions of 136–214 kg CO<sub>2</sub>-eq/m<sup>3</sup>, an eco-strength efficiency (ESE) of 0.038–0.053 MPa/(kg CO<sub>2</sub>-eq·m<sup>−3</sup>), and a cumulative energy demand (CED) of 1095–1537 MJ/m<sup>3</sup>. Both the ESE and CED metrics outperform those of conventional high-strength ordinary Portland cement-based controlled low-strength materials (CLSMs). The raw material cost is 224–307 CNY/m<sup>3</sup>, and the use of SDWS further reduces costs. This study provides an innovative and sustainable solution for flowable fill, supporting the green transformation and sustainable development of the construction industry.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"46 ","pages":"Article 102125"},"PeriodicalIF":5.8000,"publicationDate":"2025-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green innovation: Clean conversion of shield-discharged waste soil and industrial solid waste into environmentally friendly high-performance flowable fill\",\"authors\":\"Guijie Zhao , Hongzhan Guan , Huan Yan , Jinfeng Tian , Yafei Han , Jiaqi Wang , Yunkai Ruan , Liang Zhao , Feng Chen\",\"doi\":\"10.1016/j.scp.2025.102125\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>To address the high resource consumption and environmental burden of traditional fill materials, this study presents an environmentally friendly flowable fill using shield-discharged waste soil (SDWS), ground granulated blast-furnace slag (GGBFS), and fly ash as the main raw materials activated by a NaOH–Na<sub>2</sub>SiO<sub>3</sub> composite. Microstructural analysis, performance testing, and life cycle assessment (LCA) were conducted to systematically evaluate the reaction mechanisms, engineering properties, environmental impacts, and economic viability of the developed material. The results show that the prepared flowable fill has excellent workability and mechanical properties, with an initial flowability of 602–755 mm and a 28-day compressive strength of 6.43–8.98 MPa. The aggregate-to-binder ratio and alkali equivalent exert a more significant effect on the compressive strength than the liquid-to-solid ratio and activator modulus do. Microstructural analysis indicates that GGBFS and fly ash, under alkali activation, synergistically form dense C–S–H and C–A–S–H gels, improving the properties of the material. The LCA results reveal that the flowable fill achieves carbon dioxide equivalent (CO<sub>2</sub>-eq) emissions of 136–214 kg CO<sub>2</sub>-eq/m<sup>3</sup>, an eco-strength efficiency (ESE) of 0.038–0.053 MPa/(kg CO<sub>2</sub>-eq·m<sup>−3</sup>), and a cumulative energy demand (CED) of 1095–1537 MJ/m<sup>3</sup>. Both the ESE and CED metrics outperform those of conventional high-strength ordinary Portland cement-based controlled low-strength materials (CLSMs). The raw material cost is 224–307 CNY/m<sup>3</sup>, and the use of SDWS further reduces costs. This study provides an innovative and sustainable solution for flowable fill, supporting the green transformation and sustainable development of the construction industry.</div></div>\",\"PeriodicalId\":22138,\"journal\":{\"name\":\"Sustainable Chemistry and Pharmacy\",\"volume\":\"46 \",\"pages\":\"Article 102125\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-07-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Chemistry and Pharmacy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352554125002232\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Chemistry and Pharmacy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352554125002232","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Green innovation: Clean conversion of shield-discharged waste soil and industrial solid waste into environmentally friendly high-performance flowable fill
To address the high resource consumption and environmental burden of traditional fill materials, this study presents an environmentally friendly flowable fill using shield-discharged waste soil (SDWS), ground granulated blast-furnace slag (GGBFS), and fly ash as the main raw materials activated by a NaOH–Na2SiO3 composite. Microstructural analysis, performance testing, and life cycle assessment (LCA) were conducted to systematically evaluate the reaction mechanisms, engineering properties, environmental impacts, and economic viability of the developed material. The results show that the prepared flowable fill has excellent workability and mechanical properties, with an initial flowability of 602–755 mm and a 28-day compressive strength of 6.43–8.98 MPa. The aggregate-to-binder ratio and alkali equivalent exert a more significant effect on the compressive strength than the liquid-to-solid ratio and activator modulus do. Microstructural analysis indicates that GGBFS and fly ash, under alkali activation, synergistically form dense C–S–H and C–A–S–H gels, improving the properties of the material. The LCA results reveal that the flowable fill achieves carbon dioxide equivalent (CO2-eq) emissions of 136–214 kg CO2-eq/m3, an eco-strength efficiency (ESE) of 0.038–0.053 MPa/(kg CO2-eq·m−3), and a cumulative energy demand (CED) of 1095–1537 MJ/m3. Both the ESE and CED metrics outperform those of conventional high-strength ordinary Portland cement-based controlled low-strength materials (CLSMs). The raw material cost is 224–307 CNY/m3, and the use of SDWS further reduces costs. This study provides an innovative and sustainable solution for flowable fill, supporting the green transformation and sustainable development of the construction industry.
期刊介绍:
Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.