锡掺杂镍氧化铁纳米材料作为一种高效的双功能整体水分解电催化剂

Jyothi S. Doddamani , Khaleel Ahmed J. Dilshad , Smita Gajanan Naik , M.K. Rabinal , R.M. Hodlur
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引用次数: 0

摘要

过渡金属氧化物,特别是基于镍和铁的过渡金属氧化物,是很有前途的水分解反应催化剂。然而,设计高效的双功能电极用于整体水分解仍然是一个重大挑战。本研究主要通过简单的喷雾热解技术合成锡掺杂镍氧化铁,探索其作为双功能电催化剂的功效。合成的金属氧化物表现出优异的催化性能,析氧反应的过电位为230 mV,析氢反应的过电位为277 mV。此外,该材料表现出优异的稳定性,在1.7 V的施加电位下保持连续和不间断运行超过7天,提供10 mA/cm2的电流密度。该材料易于合成,具有高催化活性和耐用性,突显了其作为一种经济高效的水分解应用候选材料的潜力。通过简化制备过程,这种方法为开发可再生氢生产的可扩展和可持续解决方案提供了切实可行的途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Tin doped nickel iron oxide nanomaterials as an efficient bifunctional electrocatalyst for overall watersplitting
Transition metal oxides, particularly those based on nickel and iron, are promising catalysts for water splitting reactions. However, designing efficient bifunctional electrodes for overall water splitting remains a significant challenge. This study focuses on the synthesis of tin-doped nickel iron oxide via a simple spray pyrolysis technique to explore its efficacy as a bifunctional electrocatalyst. The synthesized metal oxide demonstrated remarkable catalytic performance, with overpotential of 230 mV for the oxygen evolution (OER) and 277 mV for the hydrogen evolution reaction (HER). Furthermore, the material exhibited excellent stability, maintain continuous and uninterrupted operation for over seven days at an applied potential of 1.7 V, delivering a current density of 10 mA/cm2. The ease of synthesis, combined with the material’s high catalytic activity and durability, highlights its potential as a cost-effective and efficient candidate for water splitting applications. By simplifying the preparation process, this approach offers a practical pathway toward developing scalable and sustainable solutions for renewable hydrogen production.
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