Jyothi S. Doddamani , Khaleel Ahmed J. Dilshad , Smita Gajanan Naik , M.K. Rabinal , R.M. Hodlur
{"title":"锡掺杂镍氧化铁纳米材料作为一种高效的双功能整体水分解电催化剂","authors":"Jyothi S. Doddamani , Khaleel Ahmed J. Dilshad , Smita Gajanan Naik , M.K. Rabinal , R.M. Hodlur","doi":"10.1016/j.nxnano.2025.100224","DOIUrl":null,"url":null,"abstract":"<div><div>Transition metal oxides, particularly those based on nickel and iron, are promising catalysts for water splitting reactions. However, designing efficient bifunctional electrodes for overall water splitting remains a significant challenge. This study focuses on the synthesis of tin-doped nickel iron oxide via a simple spray pyrolysis technique to explore its efficacy as a bifunctional electrocatalyst. The synthesized metal oxide demonstrated remarkable catalytic performance, with overpotential of 230 mV for the oxygen evolution (OER) and 277 mV for the hydrogen evolution reaction (HER). Furthermore, the material exhibited excellent stability, maintain continuous and uninterrupted operation for over seven days at an applied potential of 1.7 V, delivering a current density of 10 mA/cm<sup>2</sup>. The ease of synthesis, combined with the material’s high catalytic activity and durability, highlights its potential as a cost-effective and efficient candidate for water splitting applications. By simplifying the preparation process, this approach offers a practical pathway toward developing scalable and sustainable solutions for renewable hydrogen production.</div></div>","PeriodicalId":100959,"journal":{"name":"Next Nanotechnology","volume":"8 ","pages":"Article 100224"},"PeriodicalIF":0.0000,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Tin doped nickel iron oxide nanomaterials as an efficient bifunctional electrocatalyst for overall watersplitting\",\"authors\":\"Jyothi S. Doddamani , Khaleel Ahmed J. Dilshad , Smita Gajanan Naik , M.K. Rabinal , R.M. Hodlur\",\"doi\":\"10.1016/j.nxnano.2025.100224\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Transition metal oxides, particularly those based on nickel and iron, are promising catalysts for water splitting reactions. However, designing efficient bifunctional electrodes for overall water splitting remains a significant challenge. This study focuses on the synthesis of tin-doped nickel iron oxide via a simple spray pyrolysis technique to explore its efficacy as a bifunctional electrocatalyst. The synthesized metal oxide demonstrated remarkable catalytic performance, with overpotential of 230 mV for the oxygen evolution (OER) and 277 mV for the hydrogen evolution reaction (HER). Furthermore, the material exhibited excellent stability, maintain continuous and uninterrupted operation for over seven days at an applied potential of 1.7 V, delivering a current density of 10 mA/cm<sup>2</sup>. The ease of synthesis, combined with the material’s high catalytic activity and durability, highlights its potential as a cost-effective and efficient candidate for water splitting applications. By simplifying the preparation process, this approach offers a practical pathway toward developing scalable and sustainable solutions for renewable hydrogen production.</div></div>\",\"PeriodicalId\":100959,\"journal\":{\"name\":\"Next Nanotechnology\",\"volume\":\"8 \",\"pages\":\"Article 100224\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Next Nanotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949829525000932\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Next Nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949829525000932","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Tin doped nickel iron oxide nanomaterials as an efficient bifunctional electrocatalyst for overall watersplitting
Transition metal oxides, particularly those based on nickel and iron, are promising catalysts for water splitting reactions. However, designing efficient bifunctional electrodes for overall water splitting remains a significant challenge. This study focuses on the synthesis of tin-doped nickel iron oxide via a simple spray pyrolysis technique to explore its efficacy as a bifunctional electrocatalyst. The synthesized metal oxide demonstrated remarkable catalytic performance, with overpotential of 230 mV for the oxygen evolution (OER) and 277 mV for the hydrogen evolution reaction (HER). Furthermore, the material exhibited excellent stability, maintain continuous and uninterrupted operation for over seven days at an applied potential of 1.7 V, delivering a current density of 10 mA/cm2. The ease of synthesis, combined with the material’s high catalytic activity and durability, highlights its potential as a cost-effective and efficient candidate for water splitting applications. By simplifying the preparation process, this approach offers a practical pathway toward developing scalable and sustainable solutions for renewable hydrogen production.