Aspen Plus建模的MILENA双流化床生物质气化炉技术

Q1 Chemical Engineering
Mohadeseh Naderi , Hamid Rashidi , Anthony Reynolds , Wayne Doherty
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引用次数: 0

摘要

荷兰能源研究中心正在开发MILENA气化技术,将生物质燃料转化为高价值的气体和液体产品。MILENA是一种蒸汽吹制双流化床(DFB)气化工艺,具有单独的气化和燃烧区。该DFB气化炉生产高质量的低氮气含量的气体,适用于汽车燃料或天然气网格喷射。本研究提出了一个半动力学的Aspen Plus模型,用于MILENA气化,包括干燥、快速热解、气化、燃烧、焦油裂解和重整等阶段。热解作为关键步骤,利用木材快速热解的实验数据进行建模,计算气体、炭和焦油的产率。气化步骤建模为连续搅拌槽反应器(CSTR),并考虑了反应动力学。模拟结果包括产物气体成分、质量流量和焦油浓度,与MILENA气化炉的实验数据进行了验证,显示出很好的一致性。H2的相对误差最小,为0.39%,CO2的相对误差最大,为4.17%,验证了模型的准确性。计算了干气混合物的低热值(LHV)。敏感性分析表明,H2随水分含量的增加而增加,支持水气转换(WGS)反应的作用。此外,STBR的变化会显著影响气体成分。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Aspen Plus modelling of the MILENA dual fluidised bed biomass gasifier technology
The Energy Research Centre of The Netherlands is developing MILENA gasification technology to convert biomass fuels into high-value gaseous and liquid products. MILENA is a steam-blown dual fluidised bed (DFB) gasification process with separate gasification and combustion zones. This DFB gasifier produces high-quality gas with low N2 content suitable for vehicle fuel or natural gas grid injection. This study presents a semi-kinetic Aspen Plus model for MILENA gasification, including stages like drying, rapid pyrolysis, gasification, combustion, and tar cracking and reforming. Pyrolysis as a key step, was modelled using experimental data for the rapid pyrolysis of wood to calculate the yields of gases, char and tar. The gasification step is modelled as a continuous stirred-tank reactor (CSTR) and considers reaction kinetics. The simulation results, including product gas composition, mass flow rate, and tar concentration, were validated against experimental data for the MILENA gasifier, showing very good agreement. A low relative error of 0.39 % was the lowest for H2 and 4.17 % was the highest for CO2 in product gas composition, validating the model’s accuracy. The lower heating value (LHV) of the dry gas mixture was calculated. Sensitivity analyses demonstrated that H2 increases with moisture content, supporting the role of the water gas shift (WGS) reaction. Additionally, variations in STBR significantly affect the gas composition.
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来源期刊
International Journal of Thermofluids
International Journal of Thermofluids Engineering-Mechanical Engineering
CiteScore
10.10
自引率
0.00%
发文量
111
审稿时长
66 days
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