R. Nandhini , M. Nagoor Meeran , R.P. Suresh Jeyakumar , T. Sumathi
{"title":"可见光敏感活性炭-金属氧化物(TiO2、WO3、NiO和ZnO)纳米催化剂降解亚甲基蓝和罗丹明B","authors":"R. Nandhini , M. Nagoor Meeran , R.P. Suresh Jeyakumar , T. Sumathi","doi":"10.1016/j.jics.2025.101919","DOIUrl":null,"url":null,"abstract":"<div><div>Hydrothermal synthesis was used to produce four metal oxide–activated carbon composites with metal oxide weights of 20 % (TiO<sub>2</sub>, WO<sub>3</sub>, NiO, and ZnO). BET, XRD, SEM, TEM, UV, PL, and FTIR were all used to learn more about the nano-catalysts. Small particle size, prolonged visible absorption in the spectral region, a narrower bandgap, and a higher surface area were all attained in an effort to create highly active visible light photocatalysts. By incorporating AC into MO nanoparticles, the bandgap can be tuned from 2.63 eV to 2.21 eV, effectively increasing the MOs' visible light activity. In comparison to ZnO-AC, WO3-AC, and NiO-AC, synthesized TiO<sub>2</sub>-AC nanoparticles degrade the pollutant by approximately 100 % within 60 min. Because of the narrow bandgap and porosity of carbon, AC accelerates the rate of degradation of MB. Additionally, a first order kinetic model, stability, and different scavengers' studies were systematically conducted to investigate the role of AC in different MOs. The photocatalyst developed in this research shows promise for large-scale wastewater treatment.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 9","pages":"Article 101919"},"PeriodicalIF":3.2000,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Visible light sensitive activated carbon-metal oxide (TiO2, WO3, NiO, and ZnO) nano-catalysts for the degradation of methylene blue and Rhodamine B\",\"authors\":\"R. Nandhini , M. Nagoor Meeran , R.P. Suresh Jeyakumar , T. Sumathi\",\"doi\":\"10.1016/j.jics.2025.101919\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Hydrothermal synthesis was used to produce four metal oxide–activated carbon composites with metal oxide weights of 20 % (TiO<sub>2</sub>, WO<sub>3</sub>, NiO, and ZnO). BET, XRD, SEM, TEM, UV, PL, and FTIR were all used to learn more about the nano-catalysts. Small particle size, prolonged visible absorption in the spectral region, a narrower bandgap, and a higher surface area were all attained in an effort to create highly active visible light photocatalysts. By incorporating AC into MO nanoparticles, the bandgap can be tuned from 2.63 eV to 2.21 eV, effectively increasing the MOs' visible light activity. In comparison to ZnO-AC, WO3-AC, and NiO-AC, synthesized TiO<sub>2</sub>-AC nanoparticles degrade the pollutant by approximately 100 % within 60 min. Because of the narrow bandgap and porosity of carbon, AC accelerates the rate of degradation of MB. Additionally, a first order kinetic model, stability, and different scavengers' studies were systematically conducted to investigate the role of AC in different MOs. The photocatalyst developed in this research shows promise for large-scale wastewater treatment.</div></div>\",\"PeriodicalId\":17276,\"journal\":{\"name\":\"Journal of the Indian Chemical Society\",\"volume\":\"102 9\",\"pages\":\"Article 101919\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Indian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0019452225003541\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Indian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0019452225003541","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Visible light sensitive activated carbon-metal oxide (TiO2, WO3, NiO, and ZnO) nano-catalysts for the degradation of methylene blue and Rhodamine B
Hydrothermal synthesis was used to produce four metal oxide–activated carbon composites with metal oxide weights of 20 % (TiO2, WO3, NiO, and ZnO). BET, XRD, SEM, TEM, UV, PL, and FTIR were all used to learn more about the nano-catalysts. Small particle size, prolonged visible absorption in the spectral region, a narrower bandgap, and a higher surface area were all attained in an effort to create highly active visible light photocatalysts. By incorporating AC into MO nanoparticles, the bandgap can be tuned from 2.63 eV to 2.21 eV, effectively increasing the MOs' visible light activity. In comparison to ZnO-AC, WO3-AC, and NiO-AC, synthesized TiO2-AC nanoparticles degrade the pollutant by approximately 100 % within 60 min. Because of the narrow bandgap and porosity of carbon, AC accelerates the rate of degradation of MB. Additionally, a first order kinetic model, stability, and different scavengers' studies were systematically conducted to investigate the role of AC in different MOs. The photocatalyst developed in this research shows promise for large-scale wastewater treatment.
期刊介绍:
The Journal of the Indian Chemical Society publishes original, fundamental, theorical, experimental research work of highest quality in all areas of chemistry, biochemistry, medicinal chemistry, electrochemistry, agrochemistry, chemical engineering and technology, food chemistry, environmental chemistry, etc.