[1,2-a][1,8]四苯基二苯并吡啶手性螺旋折叠物的合成与表征[j]。化学7/2025)

IF 2.7 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-07-17 DOI:10.1002/ajoc.202580702

Kotaro Matsumura, Masashi Hasegawa, Yoshitaka Tsuchido, Hidetoshi Kawai

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引用次数: 0

摘要

具有螺旋基序的手性四苯烯衍生物是通过将多个l型单元连接到四苯烯核心而开发出来的。这些基序采用螺旋构象，具有高荧光性。此外，取代的四苯炔核的轴向手性诱导了荧光l型单元的手性，从而产生圆偏振发光。这张封面图片说明了美丽的蝴蝶状结构的四苯基和手性四苯基衍生物由它衍生。更多细节可以在Hidetoshi Kawai及其同事的文章编号e202500409中找到。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Synthesis and Chiroptical Properties of Chiral Helical Foldamers Based on Highly Fluorescent Dibenzopyrrolo[1,2-a][1,8]naphthyridines Linked to a Tetraphenylene Core (Asian J. Org. Chem. 7/2025)

查看原文本刊更多论文

Chiral tetraphenylene derivatives featuring helical motifs were developed by linking multiple L-shaped units to a tetraphenylene core. These motifs adopted helical conformations and exhibited high fluorescence. Furthermore, the axial chirality in the substituted tetraphenylene cores induced chiroptical properties to the fluorescent L-shaped units, resulting in the emission of circularly polarized luminescence. This cover picture illustrates the beautiful butterfly-like structure of the tetraphenylene and the chiral tetraphenylene derivatives derived from it. More details can be found in article number e202500409 by Hidetoshi Kawai and co-workers.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.