丙基羧酸的电化学硒/碲环化。

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Jingwen Peng , Qingfang Chen , Xingqi Wu , Ruishan Zhan , Yanchen Chen , Meihuan Ji , Caicai Lu , Junlei Wang , Fubin Jiang , Binbin Huang
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引用次数: 0

摘要

本文报道了一种新的、可持续的丙炔羧酸硒/碲环化电化学方法,在环境条件下提供了多种有价值的硒/碲结合的不饱和γ-内酯。初步的机制研究表明,这种转化主要通过阳离子途径进行。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrochemical seleno-/tellurocyclization of propargyl carboxylic acids†

Electrochemical seleno-/tellurocyclization of propargyl carboxylic acids†
Reported herein is a novel and sustainable electrochemical seleno-/tellurocyclization of propargyl carboxylic acids, affording a diverse range of valuable Se-/Te-incorporated unsaturated γ-lactones under ambient conditions. Preliminary mechanistic studies suggest that this transformation predominantly proceeds via a cationic pathway.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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