Aaron Zhen Yao Koe , Wei Jiun Lim , Chian Yong Loh , Boon Seng Ooi
{"title":"正向渗透系统中多组分水分和养分运移的动态计算","authors":"Aaron Zhen Yao Koe , Wei Jiun Lim , Chian Yong Loh , Boon Seng Ooi","doi":"10.1016/j.memsci.2025.124444","DOIUrl":null,"url":null,"abstract":"<div><div>As aquaculture production garners more interest around the globe, the production of aquaculture effluent will continue to rise. With the presence of dilute nutrients (NH<sub>4</sub><sup>+</sup> and H<sub>2</sub>PO<sub>4</sub><sup>−</sup>) in the effluent, the recovery of said nutrients requires a dewatering process. Forward osmosis (FO) systems are good dewatering processes as they have low fouling tendencies and better reuse efficiency. With that, a method for performance simulation is required for multicomponent FO systems. Multicomponent Fickian solution-diffusion model provides a simple computation method for FO systems containing more than three ions. Preliminary experimental studies concluded that NH<sub>4</sub><sup>+</sup> transport across FO membrane relies on self-diffusion and induced diffusion caused by draw solute (Mg<sup>2+</sup>). For H<sub>2</sub>PO<sub>4</sub><sup>−</sup> ions, the transport was mainly contributed by convection as the diffusion of H<sub>2</sub>PO<sub>4</sub><sup>−</sup> across FO membrane showed positive relation with increasing water flux. Experimental validation of estimated parameters was also performed by two separate experiments. FO system performance such as water flux, reverse salt flux, nutrient rejection, and final nutrient concentration was computed and compared with experimental data. The comparison showed that the values computed were generally within 6 % of deviation with some outliers at 9 % of deviation. Dynamic computation showed the flexibility of estimated parameters as it can also predict FO system performance that operates at longer operation period and a at a higher initial volume of feed and draw solution.</div></div>","PeriodicalId":368,"journal":{"name":"Journal of Membrane Science","volume":"734 ","pages":"Article 124444"},"PeriodicalIF":8.4000,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dynamic computation of multicomponent water and nutrients transport in forward osmosis system\",\"authors\":\"Aaron Zhen Yao Koe , Wei Jiun Lim , Chian Yong Loh , Boon Seng Ooi\",\"doi\":\"10.1016/j.memsci.2025.124444\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>As aquaculture production garners more interest around the globe, the production of aquaculture effluent will continue to rise. With the presence of dilute nutrients (NH<sub>4</sub><sup>+</sup> and H<sub>2</sub>PO<sub>4</sub><sup>−</sup>) in the effluent, the recovery of said nutrients requires a dewatering process. Forward osmosis (FO) systems are good dewatering processes as they have low fouling tendencies and better reuse efficiency. With that, a method for performance simulation is required for multicomponent FO systems. Multicomponent Fickian solution-diffusion model provides a simple computation method for FO systems containing more than three ions. Preliminary experimental studies concluded that NH<sub>4</sub><sup>+</sup> transport across FO membrane relies on self-diffusion and induced diffusion caused by draw solute (Mg<sup>2+</sup>). For H<sub>2</sub>PO<sub>4</sub><sup>−</sup> ions, the transport was mainly contributed by convection as the diffusion of H<sub>2</sub>PO<sub>4</sub><sup>−</sup> across FO membrane showed positive relation with increasing water flux. Experimental validation of estimated parameters was also performed by two separate experiments. FO system performance such as water flux, reverse salt flux, nutrient rejection, and final nutrient concentration was computed and compared with experimental data. The comparison showed that the values computed were generally within 6 % of deviation with some outliers at 9 % of deviation. Dynamic computation showed the flexibility of estimated parameters as it can also predict FO system performance that operates at longer operation period and a at a higher initial volume of feed and draw solution.</div></div>\",\"PeriodicalId\":368,\"journal\":{\"name\":\"Journal of Membrane Science\",\"volume\":\"734 \",\"pages\":\"Article 124444\"},\"PeriodicalIF\":8.4000,\"publicationDate\":\"2025-07-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Membrane Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0376738825007574\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Membrane Science","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0376738825007574","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Dynamic computation of multicomponent water and nutrients transport in forward osmosis system
As aquaculture production garners more interest around the globe, the production of aquaculture effluent will continue to rise. With the presence of dilute nutrients (NH4+ and H2PO4−) in the effluent, the recovery of said nutrients requires a dewatering process. Forward osmosis (FO) systems are good dewatering processes as they have low fouling tendencies and better reuse efficiency. With that, a method for performance simulation is required for multicomponent FO systems. Multicomponent Fickian solution-diffusion model provides a simple computation method for FO systems containing more than three ions. Preliminary experimental studies concluded that NH4+ transport across FO membrane relies on self-diffusion and induced diffusion caused by draw solute (Mg2+). For H2PO4− ions, the transport was mainly contributed by convection as the diffusion of H2PO4− across FO membrane showed positive relation with increasing water flux. Experimental validation of estimated parameters was also performed by two separate experiments. FO system performance such as water flux, reverse salt flux, nutrient rejection, and final nutrient concentration was computed and compared with experimental data. The comparison showed that the values computed were generally within 6 % of deviation with some outliers at 9 % of deviation. Dynamic computation showed the flexibility of estimated parameters as it can also predict FO system performance that operates at longer operation period and a at a higher initial volume of feed and draw solution.
期刊介绍:
The Journal of Membrane Science is a publication that focuses on membrane systems and is aimed at academic and industrial chemists, chemical engineers, materials scientists, and membranologists. It publishes original research and reviews on various aspects of membrane transport, membrane formation/structure, fouling, module/process design, and processes/applications. The journal primarily focuses on the structure, function, and performance of non-biological membranes but also includes papers that relate to biological membranes. The Journal of Membrane Science publishes Full Text Papers, State-of-the-Art Reviews, Letters to the Editor, and Perspectives.