内封面:交错abc -堆叠钴-三甲烯框架加速CO2光还原(角度。化学29/2025)

Jun-Hao Wu, Xin-Hui Lu, Qian-Qian Yan, Ji-Xia Qiu, Wei Zhou, Yuan-Yuan Zhu, Xiao Wang, Sheng Zhang, Kui Li, Xing Lu
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引用次数: 0

摘要

该封面说明了具有ABC堆叠的钴-三叶烯框架光催化将CO2还原为CO和H2的催化机理。沿孔壁均匀分布的Co位点和ABC的堆积有利于分子扩散,从而加速光催化反应。该框架调节了CO2、H2O和*COOH中间体的运输,而H2O和CO2之间的氢键结合碳酸盐的形成使金属活性位点的CO2浓度增加,促进了还原过程,如Wei Zhou, Xiao Wang, Xing Lu等在他们的Research Article (e202504155)中报道的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Inside Front Cover: Staggered ABC-Stacking Cobalt-Triptycene Framework for Accelerating CO2 Photoreduction (Angew. Chem. 29/2025)

Inside Front Cover: Staggered ABC-Stacking Cobalt-Triptycene Framework for Accelerating CO2 Photoreduction (Angew. Chem. 29/2025)

The cover illustrates the catalytic mechanism of a cobalt-triptycene framework with ABC stacking for the photocatalytic reduction of CO2 to CO and H2. Uniformly distributed Co sites along the pore walls and the ABC stacking facilitate molecular diffusion, thereby accelerating the photocatalytic reaction. The framework regulates the transport of CO2, H2O, and *COOH intermediates, while hydrogen bonding between H2O and CO2 coupled with carbonate formation enriches CO2 concentration at metal active sites, promoting the reduction process, as reported by Wei Zhou, Xiao Wang, Xing Lu et al. in their Research Article (e202504155).

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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