Jialong Cui , Bin Du , Yue Sun , Zexi Shao , Luchao Pei , Xinyu Bu , Zhe Wang , Bin Liang , Yuzhou Liu , Ruitao Wang , Yanji Zhu , Huaiyuan Wang
{"title":"用于CCUS的自修复复合涂层:在恶劣环境下的协同防腐和耐久性","authors":"Jialong Cui , Bin Du , Yue Sun , Zexi Shao , Luchao Pei , Xinyu Bu , Zhe Wang , Bin Liang , Yuzhou Liu , Ruitao Wang , Yanji Zhu , Huaiyuan Wang","doi":"10.1016/j.coco.2025.102519","DOIUrl":null,"url":null,"abstract":"<div><div>Carbon Capture, Utilization and Storage (CCUS) technology emerges as a promising solution amid global efforts to mitigate emissions and enhance energy efficiency. However, within the CCUS framework, metal transport pipelines encounter significant corrosion challenges, particularly in high-pressure CO<sub>2</sub> corrosion environments. Here, a novel composite filler was prepared by modifying <em>α</em>-ZrP nanosheets with tannic acid (TA) and octadecylamine (ODA), and then introduced into epoxy resin (EP) to obtain the self-healing multifunctional anti-corrosive coating named ZPO/EP. Compared to pure EP, it reduces CO<sub>2</sub> and water vapor permeability by 69.77 % and 65.16 %, respectively, and the cohesion between the resin and filler has been significantly improved, resulting in a reduction of coating defects and enhancement in the adhesion between the coating and the metal substrate. Most importantly, the coating exhibits excellent long-term anti-corrosion performance under simulated CCUS conditions. After being exposed to these conditions for 30 days, its impedance value reaches 7.25×10<sup>10</sup> Ω·cm<sup>2</sup> at 0.01 HZ<sub>.</sub> Meanwhile, the polyphenol groups of the ZPO filler can chelate with Fe<sup>2+</sup>, endowing the coating with self-healing properties. This study offers an effective solution for corrosion protection of equipment in CCUS systems, which is crucial for promoting the large-scale application and sustainable development of CCUS technology.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"58 ","pages":"Article 102519"},"PeriodicalIF":7.7000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A self-healing composite coating for CCUS: Synergistic anticorrosion and durability in harsh environments\",\"authors\":\"Jialong Cui , Bin Du , Yue Sun , Zexi Shao , Luchao Pei , Xinyu Bu , Zhe Wang , Bin Liang , Yuzhou Liu , Ruitao Wang , Yanji Zhu , Huaiyuan Wang\",\"doi\":\"10.1016/j.coco.2025.102519\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carbon Capture, Utilization and Storage (CCUS) technology emerges as a promising solution amid global efforts to mitigate emissions and enhance energy efficiency. However, within the CCUS framework, metal transport pipelines encounter significant corrosion challenges, particularly in high-pressure CO<sub>2</sub> corrosion environments. Here, a novel composite filler was prepared by modifying <em>α</em>-ZrP nanosheets with tannic acid (TA) and octadecylamine (ODA), and then introduced into epoxy resin (EP) to obtain the self-healing multifunctional anti-corrosive coating named ZPO/EP. Compared to pure EP, it reduces CO<sub>2</sub> and water vapor permeability by 69.77 % and 65.16 %, respectively, and the cohesion between the resin and filler has been significantly improved, resulting in a reduction of coating defects and enhancement in the adhesion between the coating and the metal substrate. Most importantly, the coating exhibits excellent long-term anti-corrosion performance under simulated CCUS conditions. After being exposed to these conditions for 30 days, its impedance value reaches 7.25×10<sup>10</sup> Ω·cm<sup>2</sup> at 0.01 HZ<sub>.</sub> Meanwhile, the polyphenol groups of the ZPO filler can chelate with Fe<sup>2+</sup>, endowing the coating with self-healing properties. This study offers an effective solution for corrosion protection of equipment in CCUS systems, which is crucial for promoting the large-scale application and sustainable development of CCUS technology.</div></div>\",\"PeriodicalId\":10533,\"journal\":{\"name\":\"Composites Communications\",\"volume\":\"58 \",\"pages\":\"Article 102519\"},\"PeriodicalIF\":7.7000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2452213925002724\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Communications","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2452213925002724","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
A self-healing composite coating for CCUS: Synergistic anticorrosion and durability in harsh environments
Carbon Capture, Utilization and Storage (CCUS) technology emerges as a promising solution amid global efforts to mitigate emissions and enhance energy efficiency. However, within the CCUS framework, metal transport pipelines encounter significant corrosion challenges, particularly in high-pressure CO2 corrosion environments. Here, a novel composite filler was prepared by modifying α-ZrP nanosheets with tannic acid (TA) and octadecylamine (ODA), and then introduced into epoxy resin (EP) to obtain the self-healing multifunctional anti-corrosive coating named ZPO/EP. Compared to pure EP, it reduces CO2 and water vapor permeability by 69.77 % and 65.16 %, respectively, and the cohesion between the resin and filler has been significantly improved, resulting in a reduction of coating defects and enhancement in the adhesion between the coating and the metal substrate. Most importantly, the coating exhibits excellent long-term anti-corrosion performance under simulated CCUS conditions. After being exposed to these conditions for 30 days, its impedance value reaches 7.25×1010 Ω·cm2 at 0.01 HZ. Meanwhile, the polyphenol groups of the ZPO filler can chelate with Fe2+, endowing the coating with self-healing properties. This study offers an effective solution for corrosion protection of equipment in CCUS systems, which is crucial for promoting the large-scale application and sustainable development of CCUS technology.
期刊介绍:
Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.