Zhaoxi Li , Yi Guo , Jiarong Zhang , Jiangtao Xiong , Wei Guo , Jinglong Li
{"title":"TA37/TC19合金扩散键合中的热循环配位:显微组织和力学见解","authors":"Zhaoxi Li , Yi Guo , Jiarong Zhang , Jiangtao Xiong , Wei Guo , Jinglong Li","doi":"10.1016/j.matchar.2025.115369","DOIUrl":null,"url":null,"abstract":"<div><div>To meet the stringent demands of next-generation aeroengines, this paper has developed solid diffusion-bonded joints potentially used in centrifugal impellers by joining the high-temperature titanium alloy TA37 to the high-strength alloy TC19. Given the intrinsic divergence in heat-treatment requirements between two alloys—where TA37 relies on high-temperature solution treatment while TC19 demands precise aging to refine α/β lamellae—we systematically compared two diffusion bonding protocols with a basic process of 860 °C, 20 MPa for 60 min. The first strategy utilized as-received wrought base materials without additional processing, representing conventional industrial practice. In contrast, the other implemented a harmonized thermal sequence: TA37 underwent pre-bonding solution treatment (1033 °C/2 h, WQ) to activate nano-silicide formation, while TC19 received post-bonding solution-aging (930 °C/2 h, AQ + 593 °C/8 h, AC) to preserve phase stability. This coordinated approach aimed to reconcile the alloys' conflicting thermal histories and mitigate interfacial degradation. We systematically characterized the joints' interfacial morphology, microstructure evolution, and mechanical behavior using SEM, TEM, EBSD, EPMA, nanoindentation, and in-situ tensile testing. In both cases, a diffusion-affected zone approximately 10 μm thick formed at the interface, within which the TC19 alloy developed a duplex α + β structure. Crucially, the heat-treatment-modified joint achieved a tensile strength of 1076 MPa, significantly higher than the 959 MPa measured for the joint bonded using as-wrought materials. In-situ tensile experiments revealed that deformation proceeds via cooperative yielding of the α and β phases across the bonded region, confirming that the modified thermal cycle promotes uniform load sharing and suppresses localized strain concentrations. Together, these results demonstrate that integrating pre- and post-bonding heat treatments with the diffusion-bonding cycle markedly enhances joint performance. This work thus provides a practical framework for optimizing heat-treatment schedules in the diffusion bonding of dissimilar titanium alloys, laying a foundation for designing high-performance dual-alloy components in advanced aeroengine architectures.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"228 ","pages":"Article 115369"},"PeriodicalIF":4.8000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermal cycle coordination in diffusion bonding of TA37/TC19 alloys: microstructural and mechanical insights\",\"authors\":\"Zhaoxi Li , Yi Guo , Jiarong Zhang , Jiangtao Xiong , Wei Guo , Jinglong Li\",\"doi\":\"10.1016/j.matchar.2025.115369\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>To meet the stringent demands of next-generation aeroengines, this paper has developed solid diffusion-bonded joints potentially used in centrifugal impellers by joining the high-temperature titanium alloy TA37 to the high-strength alloy TC19. Given the intrinsic divergence in heat-treatment requirements between two alloys—where TA37 relies on high-temperature solution treatment while TC19 demands precise aging to refine α/β lamellae—we systematically compared two diffusion bonding protocols with a basic process of 860 °C, 20 MPa for 60 min. The first strategy utilized as-received wrought base materials without additional processing, representing conventional industrial practice. In contrast, the other implemented a harmonized thermal sequence: TA37 underwent pre-bonding solution treatment (1033 °C/2 h, WQ) to activate nano-silicide formation, while TC19 received post-bonding solution-aging (930 °C/2 h, AQ + 593 °C/8 h, AC) to preserve phase stability. This coordinated approach aimed to reconcile the alloys' conflicting thermal histories and mitigate interfacial degradation. We systematically characterized the joints' interfacial morphology, microstructure evolution, and mechanical behavior using SEM, TEM, EBSD, EPMA, nanoindentation, and in-situ tensile testing. In both cases, a diffusion-affected zone approximately 10 μm thick formed at the interface, within which the TC19 alloy developed a duplex α + β structure. Crucially, the heat-treatment-modified joint achieved a tensile strength of 1076 MPa, significantly higher than the 959 MPa measured for the joint bonded using as-wrought materials. In-situ tensile experiments revealed that deformation proceeds via cooperative yielding of the α and β phases across the bonded region, confirming that the modified thermal cycle promotes uniform load sharing and suppresses localized strain concentrations. Together, these results demonstrate that integrating pre- and post-bonding heat treatments with the diffusion-bonding cycle markedly enhances joint performance. This work thus provides a practical framework for optimizing heat-treatment schedules in the diffusion bonding of dissimilar titanium alloys, laying a foundation for designing high-performance dual-alloy components in advanced aeroengine architectures.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"228 \",\"pages\":\"Article 115369\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325006588\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325006588","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Thermal cycle coordination in diffusion bonding of TA37/TC19 alloys: microstructural and mechanical insights
To meet the stringent demands of next-generation aeroengines, this paper has developed solid diffusion-bonded joints potentially used in centrifugal impellers by joining the high-temperature titanium alloy TA37 to the high-strength alloy TC19. Given the intrinsic divergence in heat-treatment requirements between two alloys—where TA37 relies on high-temperature solution treatment while TC19 demands precise aging to refine α/β lamellae—we systematically compared two diffusion bonding protocols with a basic process of 860 °C, 20 MPa for 60 min. The first strategy utilized as-received wrought base materials without additional processing, representing conventional industrial practice. In contrast, the other implemented a harmonized thermal sequence: TA37 underwent pre-bonding solution treatment (1033 °C/2 h, WQ) to activate nano-silicide formation, while TC19 received post-bonding solution-aging (930 °C/2 h, AQ + 593 °C/8 h, AC) to preserve phase stability. This coordinated approach aimed to reconcile the alloys' conflicting thermal histories and mitigate interfacial degradation. We systematically characterized the joints' interfacial morphology, microstructure evolution, and mechanical behavior using SEM, TEM, EBSD, EPMA, nanoindentation, and in-situ tensile testing. In both cases, a diffusion-affected zone approximately 10 μm thick formed at the interface, within which the TC19 alloy developed a duplex α + β structure. Crucially, the heat-treatment-modified joint achieved a tensile strength of 1076 MPa, significantly higher than the 959 MPa measured for the joint bonded using as-wrought materials. In-situ tensile experiments revealed that deformation proceeds via cooperative yielding of the α and β phases across the bonded region, confirming that the modified thermal cycle promotes uniform load sharing and suppresses localized strain concentrations. Together, these results demonstrate that integrating pre- and post-bonding heat treatments with the diffusion-bonding cycle markedly enhances joint performance. This work thus provides a practical framework for optimizing heat-treatment schedules in the diffusion bonding of dissimilar titanium alloys, laying a foundation for designing high-performance dual-alloy components in advanced aeroengine architectures.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.